Total synthesis of (±)-Lingzhilactone B via semipinacol rearrangement

被引：14
|
作者：
Chen, Dong [1 ,2 ]
Li, Xiao-Mei [1 ,2 ]
Liu, Hao-Miao [1 ,2 ]
Li, Ming-Ming [3 ]
Cheng, Yong-Xian [1 ]
Qin, Hong-Bo [1 ]
机构：
[1] Chinese Acad Sci, Kunming Inst Bot, State Key Lab Photochem & Plant Resources West Ch, Kunming 650201, Yunnan, Peoples R China
[2] Univ Chinese Acad Sci, Beijing 100049, Peoples R China
[3] Yunnan Baiyao Grp Corp Ltd, Kunming 650032, Peoples R China
来源：
TETRAHEDRON LETTERS | 2016年 / 57卷 / 26期
基金：
中国国家自然科学基金; 中国科学院西部之光基金;
关键词：
Total synthesis; Lingzhilactone B; Semipinacol rearrangement;
D O I：
10.1016/j.tetlet.2016.05.063
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Total synthesis of (+/-)-Lingzhilactone B has been achieved for the first time in 13 steps. The key step features a semipinacol rearrangement to construct 5/5 bicyclic ring with adjacent quaternary carbon. (C) 2016 Elsevier Ltd. All rights reserved.
引用
收藏
页码：2877 / 2879
页数：3
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