Garnet type Y2Mg3Ge3O12: Dy3+/Eu3+ phosphors excited near ultraviolet: Luminescence properties and energy transfer mechanisms

被引:12
作者
Wang, Zhongxue [1 ]
Cheng, Liqun [2 ]
Tang, He [1 ]
Yu, Xiaofang [1 ]
Xie, Jihuan [1 ]
Mi, Xiaoyun [1 ]
Liu, Quansheng [1 ]
Zhang, Xiyan [1 ]
机构
[1] Changchun Univ Sci & Technol, Sch Mat Sci & Engn, Changchun 130022, Peoples R China
[2] Changchun Univ Sci & Technol, Int Res Ctr Nano Handling & Mfg China, Changchun 130022, Peoples R China
关键词
Y2Mg3Ge3O12; phosphor; Photoluminescence; Energy transfer; Excellent thermal stability; WHITE-LIGHT EMISSION; PHOTOLUMINESCENCE PROPERTIES; EU3+ PHOSPHORS; DY3+; NANOPHOSPHORS; TEMPERATURE; IONS; SR;
D O I
10.1016/j.jssc.2021.122295
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
A battery of Dy3+ single-doped and Dy3+/Eu3+ co-doped Y2Mg3Ge3O12 phosphors were manufactured by hightemperature solid-phase method. The XRD patterns were tested and Rietveld refined. When the samples were excited by 352 nm near ultraviolet light, the energy transfer efficiency can reach 83.2%, and the energy transfer mechanism is electric dipole-electric dipole interaction. The thermal stability of Y1.75Mg3Ge3O12:0.05Dy(3+), 0.2Eu(3+) was tested. When the temperature reached 150 degrees C, its luminous intensity droped to 92.4% of the initial temperature (30 degrees C). By changing the concentrations of Eu3+, white light with red light can be obtained. The above results indicate that these samples are expected to become candidate materials in the domain of solid-state lighting.
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页数:8
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