2,3-Dihydroimidazol-2-ylidenes and their main group element chemistry

被引：231

作者：

Kuhn, N ^{[1
]}

Al-Sheikh, A ^{[1
]}

机构：

[1] Univ Tubingen, Inst Anorgan Chem, D-72076 Tubingen, Germany

来源：

COORDINATION CHEMISTRY REVIEWS | 2005年 / 249卷 / 7-8期

关键词：

carbenes; heterocycles; main group elements; carbene complexes;

D O I：

10.1016/j.ccr.2004.10.003

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The coordination chemistry of stable or in situ accessible carbenes is still rapidly developing. Owing to their strong basicity, they may act both as ligands in coordination compounds and as bases or reducing agents. This report reviews the reactions of 2,3-dihydroinudazol-2ylidenes with main group element compounds and the reactions of the resultant products. A list of compounds including information about synthesis and instrumental analysis is given at the end of the report. (c) 2004 Elsevier B.V. All rights reserved.

引用

页码：829 / 857

页数：29

共 243 条

[71] 2-M
[72] Reactions of N-methylbenzothiazole-2(3H)-thione (1) and -selone (2) with ICl -: Synthesis and X-ray crystal structures of the charge-transfer adducts 1•ICl (I) and 2•ICl (II)
Demartin, F
Devillanova, FA
Garau, A
Isaia, F
Lippolis, V
Verani, G
[J]. POLYHEDRON, 1999, 18 (24) : 3107 - 3113
[73] Denk MK, 2003, EUR J INORG CHEM, P224
[74] Synthesis and reactivity of subvalent compounds Part 11. Oxidation, hydrogenation and hydrolysis of stable diamino carbenes
Denk, MK
Rodezno, JM
Gupta, S
Lough, AJ
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2001, 617 (01) : 242 - 253
[75] Synthesis and reactivity of subvalent compounds Part 10. Fast deuterium labeling and the basicity of stable diamino carbenes (imidazole-2-ylidenes)
Denk, MK
Rodezno, JM
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2001, 617 (01) : 737 - 740
[76] Denk MK, 2001, CHEM-EUR J, V7, P4477, DOI 10.1002/1521-3765(20011015)7:20<4477::AID-CHEM4477>3.0.CO
[77] 2-I
[78] Synthesis and reactivity of subvalent compounds - Part 10. Fast deuterium labeling and the basicity of stable diamino carbenes (imidazole-2-ylidenes)
Denk, MK
Rodezno, JM
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2000, 608 (1-2) : 122 - 125
[79] Structural and Raman spectroscopic studies as complementary tools in elucidating the nature of the bonding in polyiodides and in donor-I2 adducts
Deplano, P
Ferraro, JR
Mercuri, ML
Trogu, EF
[J]. COORDINATION CHEMISTRY REVIEWS, 1999, 188 : 71 - 95
[80] Tuning selenium-iodine contacts:: from secondary soft-soft interactions to covalent bonds
du Mont, WW
Martens-von Salzen, A
Ruthe, F
Seppälä, E
Mugesh, G
Devillanova, FA
Lippolis, V
Kuhn, N
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2001, 623 (1-2) : 14 - 28

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