2,3-Dihydroimidazol-2-ylidenes and their main group element chemistry

被引:231
作者
Kuhn, N [1 ]
Al-Sheikh, A [1 ]
机构
[1] Univ Tubingen, Inst Anorgan Chem, D-72076 Tubingen, Germany
关键词
carbenes; heterocycles; main group elements; carbene complexes;
D O I
10.1016/j.ccr.2004.10.003
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The coordination chemistry of stable or in situ accessible carbenes is still rapidly developing. Owing to their strong basicity, they may act both as ligands in coordination compounds and as bases or reducing agents. This report reviews the reactions of 2,3-dihydroinudazol-2ylidenes with main group element compounds and the reactions of the resultant products. A list of compounds including information about synthesis and instrumental analysis is given at the end of the report. (c) 2004 Elsevier B.V. All rights reserved.
引用
收藏
页码:829 / 857
页数:29
相关论文
共 243 条
[1]   UPON THE STRUCTURE OF ROOM-TEMPERATURE HALOGENOALUMINATE IONIC LIQUIDS [J].
ABDULSADA, AK ;
GREENWAY, AM ;
HITCHCOCK, PB ;
MOHAMMED, TJ ;
SEDDON, KR ;
ZORA, JA .
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1986, (24) :1753-1754
[2]   Preparation, characterization, and reactivity of the stable indium trihydride complex [InH3{CN(Mes)C2H2N(Mes)}] [J].
Abernethy, CD ;
Cole, ML ;
Jones, C .
ORGANOMETALLICS, 2000, 19 (23) :4852-4857
[3]   Selective reductions with stable indium trihydride reagents [J].
Abernethy, CD ;
Cole, ML ;
Davies, AJ ;
Jones, C .
TETRAHEDRON LETTERS, 2000, 41 (39) :7567-7570
[4]   A persistent C-H•••C(π) t-stacked cation [J].
Abernethy, CD ;
Macdonald, CLB ;
Clyburne, JAC ;
Cowley, AH .
CHEMICAL COMMUNICATIONS, 2001, (01) :61-62
[5]   STABLE CARBENES AS STRONG BASES [J].
ALDER, RW ;
ALLEN, PR ;
WILLIAMS, SJ .
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1995, (12) :1267-1268
[6]   Complexation of stable carbenes with alkali metals [J].
Alder, RW ;
Blake, ME ;
Bortolotti, C ;
Bufali, S ;
Butts, CP ;
Linehan, E ;
Oliva, JM ;
Orpen, AG ;
Quayle, MJ .
CHEMICAL COMMUNICATIONS, 1999, (03) :241-242
[7]   An N-heterocyclic carbene ligand with flexible steric bulk allows Suzuki cross-coupling of sterically hindered aryl chlorides at room temperature [J].
Altenhoff, G ;
Goddard, R ;
Lehmann, CW ;
Glorius, F .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2003, 42 (31) :3690-3693
[8]  
[Anonymous], TRENDS INORG CHEM
[9]  
ANSELL GB, 1970, CHEM COMMUN, P56
[10]   Charge-transfer adducts between donors containing chalcogens (S and Se) and di-iodine: solution studies [J].
Aragoni, MC ;
Arca, M ;
Devillanova, FA ;
Garau, A ;
Isaia, F ;
Lippolis, V ;
Verani, G .
COORDINATION CHEMISTRY REVIEWS, 1999, 184 :271-290