Mutual solubilities of terpene in methanol and water and their multicomponent liquid-liquid equilibria

被引：35
|
作者：
Tamura, K [1 ]
Li, HD [1 ]
机构：
[1] Kanazawa Univ, Dept Chem & Chem Engn, Div Mat Engn & Mat Sci, Grad Sch Nat Sci & Technol, Kanazawa, Ishikawa 9201192, Japan
来源：
JOURNAL OF CHEMICAL AND ENGINEERING DATA | 2005年 / 50卷 / 06期
关键词：
D O I：
10.1021/je0502391
中图分类号：
O414.1 [热力学];
学科分类号：
摘要：
Multicomponent liquid-liquid equilibria measured at T = 298.15 K have been reported for the ternary (water + methanol + alpha-pinene or + beta-pinene or + limonene) and (water or methanol + alpha-pinene + limonene) systems and the quaternary (water + methanol + a-pinene + limonene) systems. The mutual solubilities of terpenes (alpha-pinene, beta-pinene, and limonene) in methanol and water have been measured at T = 298.15 K. The experimental multicomponent liquid-liquid equilibrium data have been satisfactorily represented by using the extended UNIQUAC and modified UNIQUAC models.
引用
收藏
页码：2013 / 2018
页数：6
相关论文
共 50 条
  • [41] Liquid-liquid equilibria of water plus ethanol plus reformate
    de Doz, MBG
    Bonatti, CM
    Sólimo, HN
    FLUID PHASE EQUILIBRIA, 2005, 230 (1-2) : 45 - 50
  • [42] LIQUID-LIQUID EQUILIBRIA IN SYSTEM BENZENE-PYRIDINE-WATER
    SMITH, JC
    STIBOLT, VD
    DAY, RW
    INDUSTRIAL AND ENGINEERING CHEMISTRY, 1951, 43 (01): : 190 - 194
  • [43] LIQUID-LIQUID EQUILIBRIA OF PHENOL-WATER-SOLVENT SYSTEMS
    TAKAHASHI, S
    OTAKE, K
    TAKAHASHI, T
    IGUCHI, A
    KAGAKU KOGAKU RONBUNSHU, 1988, 14 (04) : 531 - 535
  • [44] LIQUID LIQUID EQUILIBRIA FOR THE SYSTEM BENZENE WATER-METHANOL
    TRIDAY, JO
    JOURNAL OF CHEMICAL AND ENGINEERING DATA, 1984, 29 (03): : 321 - 324
  • [45] Liquid-liquid solubilities for the binary systems of methanol with octane and 2,2,4-trimethylpentane
    Kurihara, K
    Midorikawa, T
    Hashimoto, T
    Kojima, K
    Ochi, K
    JOURNAL OF CHEMICAL ENGINEERING OF JAPAN, 2002, 35 (04) : 360 - 364
  • [46] Liquid-liquid equilibria and thermodynamic properties of the system methyl acetate plus methanol plus water at 298.15 K
    Iglesias, M
    Marino, G
    Orge, B
    Piñeiro, MM
    Tojo, J
    PHYSICS AND CHEMISTRY OF LIQUIDS, 1999, 37 (03) : 193 - 213
  • [47] Reaction and liquid-liquid distribution equilibria in oleic acid/methanol/methyl oleate/water system at 73°C
    Chen, FM
    Sun, HF
    Naka, Y
    Kawasaki, J
    JOURNAL OF CHEMICAL ENGINEERING OF JAPAN, 2001, 34 (12) : 1479 - 1485
  • [48] THE MUTUAL SOLUBILITIES OF WATER WITH SUPERCRITICAL AND LIQUID CARBON-DIOXIDE
    KING, MB
    MUBARAK, A
    KIM, JD
    BOTT, TR
    JOURNAL OF SUPERCRITICAL FLUIDS, 1992, 5 (04): : 296 - 302
  • [49] A practical method for the calculation of liquid-liquid equilibria in multicomponent organic-water-electrolyte systems using physicochemical constraints
    Zuend, Andreas
    Seinfeld, John H.
    FLUID PHASE EQUILIBRIA, 2013, 337 : 201 - 213
  • [50] Multicomponent liquid-liquid extraction kinetics
    Hartmann, T
    Kaminsky, S
    Obendorf, L
    vonReden, C
    Slater, MJ
    1997 JUBILEE RESEARCH EVENT, VOLS 1 AND 2, 1997, : 1105 - 1108
12345