Self-assembly of amphiphilic calix[4]arenes in aqueous solution

被引：88
|
作者：
Strobel, M
Kita-Tokarczyk, K
Taubert, A
Vebert, C
Heiney, PA
Chami, M
Meier, W
机构：
[1] Univ Basel, Bioctr, Dept Chem, CH-4056 Basel, Switzerland
[2] Univ Penn, Dept Phys & Astron, Philadelphia, PA 19104 USA
[3] Univ Basel, Bioctr, ME Muller Inst Microscopy, CH-4056 Basel, Switzerland
来源：
ADVANCED FUNCTIONAL MATERIALS | 2006年 / 16卷 / 02期
关键词：
D O I：
10.1002/adfm.200500212
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The self-assembly of amphiphilic calix[4]arenes with either a carboxylic acid or a trimethyl ammonium head group and different alkyl chains in aqueous solution was investigated. The carboxylated calixarene forms vesicles in dilute solution and stable monolayers on water. In contrast, the ammonium head group provides high water solubility with no observed aggregation. At high concentrations, all calixarene amphiphiles form lyotropic liquid crystals.
引用
收藏
页码：252 / 259
页数：8
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