Self-assembly of amphiphilic calix[4]arenes in aqueous solution

被引：88
|
作者：
Strobel, M
Kita-Tokarczyk, K
Taubert, A
Vebert, C
Heiney, PA
Chami, M
Meier, W
机构：
[1] Univ Basel, Bioctr, Dept Chem, CH-4056 Basel, Switzerland
[2] Univ Penn, Dept Phys & Astron, Philadelphia, PA 19104 USA
[3] Univ Basel, Bioctr, ME Muller Inst Microscopy, CH-4056 Basel, Switzerland
来源：
ADVANCED FUNCTIONAL MATERIALS | 2006年 / 16卷 / 02期
关键词：
D O I：
10.1002/adfm.200500212
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The self-assembly of amphiphilic calix[4]arenes with either a carboxylic acid or a trimethyl ammonium head group and different alkyl chains in aqueous solution was investigated. The carboxylated calixarene forms vesicles in dilute solution and stable monolayers on water. In contrast, the ammonium head group provides high water solubility with no observed aggregation. At high concentrations, all calixarene amphiphiles form lyotropic liquid crystals.
引用
收藏
页码：252 / 259
页数：8
相关论文
共 50 条
  • [1] Synthesis and self-assembly of amphiphilic semifluorinated calix[4]arenes
    Martin, OM
    Mecozzi, S
    SUPRAMOLECULAR CHEMISTRY, 2005, 17 (1-2) : 9 - 15
  • [2] Solution self-assembly and solid state properties of fluorinated amphiphilic calix[4] arenes
    Martin, OM
    Yu, L
    Mecozzi, S
    CHEMICAL COMMUNICATIONS, 2005, (39) : 4964 - 4966
  • [3] Self-assembly of amphiphilic calix[4]arenes with liquid crystalline properties.
    Martin, OM
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2005, 229 : U545 - U545
  • [4] The self-assembly of catenated calix[4]arenes
    Li, ZT
    Ji, GZ
    Yuan, SD
    Du, AL
    Ding, H
    Wei, M
    TETRAHEDRON LETTERS, 1998, 39 (36) : 6517 - 6520
  • [5] Self-assembly of amphiphilic anionic calix[4]arenes and encapsulation of poorly soluble naproxen and flurbiprofen
    Barbera, Lucia
    Gattuso, Giuseppe
    Kohnke, Franz H.
    Notti, Anna
    Pappalardo, Sebastiano
    Parisi, Melchiorre F.
    Pisagatti, Ilenia
    Patane, Salvatore
    Micali, Norberto
    Villari, Valentina
    ORGANIC & BIOMOLECULAR CHEMISTRY, 2015, 13 (23) : 6468 - 6473
  • [6] Para-acyl calix[4]arenes:: amphiphilic self-assembly from the molecular to the mesoscopic level
    Shahgaldian, P
    Cesario, M
    Goreloff, P
    Coleman, AW
    CHEMICAL COMMUNICATIONS, 2002, (04) : 326 - 327
  • [7] Self-assembly of mixed amphiphilic triblock copolymers in aqueous solution
    Liu, TB
    Nace, VM
    Chu, B
    LANGMUIR, 1999, 15 (09) : 3109 - 3117
  • [8] Tetramethoxy calix[4]arenes revisited: Conformational control through self-assembly
    Castellano, RK
    Rudkevich, DM
    Rebek, J
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1996, 118 (41) : 10002 - 10003
  • [9] Synthesis and pH-dependent self-assembly of semifluorinated calix[4]arenes
    Martin, Oana M.
    Mecozzi, Sandro
    TETRAHEDRON, 2007, 63 (25) : 5539 - 5547
  • [10] Self-aggregation in aqueous solution of amphiphilic cationic calix[4] arenes. Potential use as vectors and nanocarriers
    Ostos, Francisco J.
    Lebron, Jose A.
    Lopez-Cornejo, Pilar
    Lopez-Lopez, Manuel
    Garcia-Calderon, Margarita
    Garcia-Calderon, Clara B.
    Rosado, Ivan, V
    Kalchenko, Vitaly, I
    Rodik, Roman, V
    Luisa Moya, Maria
    JOURNAL OF MOLECULAR LIQUIDS, 2020, 304
12345