RAPID SYNTHESIS OF CoSb3/GRAPHENE NANOCOMPOSITES BY ONE-POT SOLVOTHERMAL ROUTE AND THEIR ELECTROCHEMICAL PROPERTIES

被引：2
|
作者：
Zheng, Yun-Xiao [1 ]
Xie, Jian [1 ]
Liu, Shuang-Yu [1 ]
Song, Wen-Tao [1 ]
Zhu, Tie-Jun [1 ]
Cao, Gao-Shao [1 ]
Zhao, Xin-Bing [1 ]
机构：
[1] Zhejiang Univ, Dept Mat Sci & Engn, Hangzhou 310027, Peoples R China
来源：
FUNCTIONAL MATERIALS LETTERS | 2012年 / 5卷 / 01期
基金：
中国国家自然科学基金;
关键词：
CoSb3; Graphene; nanocomposite; electrochemical properties; FILLED SKUTTERUDITE ANTIMONIDES; THERMOELECTRIC PROPERTIES; TRANSPORT-PROPERTIES; GRAPHITE OXIDE; LI STORAGE; COSB3; LITHIUM; REDUCTION; SPECTROSCOPY;
D O I：
10.1142/S1793604712500026
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
A facile synthetic approach for CoSb3/graphene nanocomposite has been developed in this work. By adjusting Co/Sb molar ratio, reaction temperature, and reaction time, we found that nanocrystalline CoSb3 (5-10 nm) can form at a low temperature of 180 degrees C and a short time of only 1 h via a one-pot solvothermal route. At the same time, graphite oxide can be reduced to graphene with uniformly loaded CoSb3 nanoparticles. The composites have been characterized by X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), field emission scanning electron microscopy (FESEM), and transmission electron microscopy (TEM). The nanocomposite shows improved cycling stability compared to bare CoSb3.
引用
收藏
页数：5
相关论文
共 50 条
  • [21] One-pot synthesis of 3D framework graphene via electrochemical method
    Liu, Yanyun
    Guo, Chao
    Zhang, Dong
    Shang, Yu
    MATERIALS LETTERS, 2014, 115 : 25 - 28
  • [22] Synthesis and thermoelectric properties of SiC/CoSb3 composites
    Li Li
    Jin Songzhe
    Li Jingfeng
    Sui Tao
    RARE METAL MATERIALS AND ENGINEERING, 2007, 36 : 398 - 400
  • [23] One-pot solvothermal synthesis of a Cu2O/Graphene nanocomposite and its application in an electrochemical sensor for dopamine
    Zhang, Fengyuan
    Li, Yongjie
    Gu, Yong-e
    Wang, Zaihua
    Wang, Chunming
    MICROCHIMICA ACTA, 2011, 173 (1-2) : 103 - 109
  • [24] One-pot solvothermal synthesis of a Cu2O/Graphene nanocomposite and its application in an electrochemical sensor for dopamine
    Fengyuan Zhang
    Yongjie Li
    Yong-e Gu
    Zaihua Wang
    Chunming Wang
    Microchimica Acta, 2011, 173 : 103 - 109
  • [25] Self-assembly of CoS2/graphene nanoarchitecture by a facile one-pot route and its improved electrochemical Li-storage properties
    Xie, Jian
    Liu, Shuangyu
    Cao, Gaoshao
    Zhu, Tiejun
    Zhao, Xinbing
    NANO ENERGY, 2013, 2 (01) : 49 - 56
  • [26] One-pot solvothermal synthesis of ZnTe/RGO nanocomposites and enhanced visible-light photocatalysis
    Wang, Hai-Xia
    Wu, Rong
    Wei, Shun-Hang
    Yu, Li-Rui
    Jian, Ji-Kang
    Hou, Juan
    Wang, Jing
    Zhang, Hong-Yan
    Sun, Yan-Fei
    CHINESE CHEMICAL LETTERS, 2016, 27 (09) : 1572 - 1576
  • [27] One-pot solvothermal synthesis of ZnTe/RGO nanocomposites and enhanced visible-light photocatalysis
    Hai-Xia Wang
    Rong Wu
    Shun-Hang Wei
    Li-Rui Yu
    Ji-Kang Jian
    Juan Hou
    Jing Wang
    Hong-Yan Zhang
    Yan-Fei Sun
    Chinese Chemical Letters, 2016, 27 (09) : 1572 - 1576
  • [28] Thermoelectric properties of n-type CoSb3 nanocomposite prepared by in situ solvothermal synthesis and hot pressing
    Mi Jian-Li
    Zhao Xin-Bing
    Zhu Tie-Jun
    Tu Jiang-Ping
    JOURNAL OF INORGANIC MATERIALS, 2008, 23 (04) : 715 - 718
  • [29] In situ one-pot synthesis of graphene-polyaniline nanofiber composite for high-performance electrochemical capacitors
    Jin, Yuhong
    Fang, Mou
    Jia, Mengqiu
    APPLIED SURFACE SCIENCE, 2014, 308 : 333 - 340
  • [30] Rapid One-Pot Synthesis and Photoelectrochemical Properties of Copper Vanadates
    Hossain, Mohammad K.
    Sotelo, Paola
    Sarker, Hori P.
    Galante, Miguel T.
    Kormanyos, Attila
    Longo, Claudia
    Macaluso, Robin T.
    Huda, Mohammad N.
    Janaky, Csaba
    Rajeshwar, Krishnan
    ACS APPLIED ENERGY MATERIALS, 2019, 2 (04) : 2837 - 2847
12345