g-C3N4/SiO2-HNb3O8 composites with enhanced photocatalytic activities for rhodamine B degradation under visible light

被引:32
作者
Pan, Huiqi [1 ,2 ,3 ]
Li, Xiukai [1 ,2 ,3 ]
Zhuang, Zongjin [1 ,2 ,3 ]
Zhang, Chi [1 ,2 ,3 ]
机构
[1] Jiangsu Univ, China Australia Joint Res Ctr Funct Mol Mat, Zhenjiang 212013, Peoples R China
[2] Jiangsu Univ, Sci Res Acad, Zhenjiang 212013, Peoples R China
[3] Jiangsu Univ, Sch Chem & Chem Engn, Zhenjiang 212013, Peoples R China
基金
中国国家自然科学基金;
关键词
Photocatalysis; Visible light; Niobic acid; g-C3N4; Composite; GRAPHITIC CARBON NITRIDE; LAMELLAR NIOBIC ACID; HYDROGEN-PRODUCTION; IRRADIATION; DECOMPOSITION; WATER; PERFORMANCE; NIOBATE; PHOTODEGRADATION; CATALYSTS;
D O I
10.1016/j.molcata.2011.05.024
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Visible light-responsive g-C3N4/SiO2-HNb3O8 composite photocatalysts were prepared by a solid state-reaction method with melamine as a g-C3N4 precursor. The photocatalytic activities of the samples were evaluated for rhodamine B (RhB) degradation under visible light irradiation and the results were compared with those obtained over pure SiO2-HNb3O8 and g-C3N4. Techniques such as XRD, FT-IR, SEM, TEM, and UV-vis diffuse reflectance spectroscopy were adopted to explore the characteristics of samples. The g-C3N4/SiO2-HNb3O8 composite materials exhibited superior activities than pure SiO2-HNb3O8 and g-C3N4; the sample prepared with SiO2-HNb3O8 to melamine ratio being 1:2 and the heating duration being 4h performed the best. The improved activity of g-C3N4/SiO2-HNb3O8 is attributed to the unique synergetic effect between SiO2-HNb3O8 and g-C3N4. (C) 2011 Elsevier B.V. All rights reserved.
引用
收藏
页码:90 / 95
页数:6
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