Gyroidal Metal-Organic Frameworks

被引：77

作者：

Zhou, Xiao-Ping ^{[1
]}

Li, Mian ^{[1
]}

Liu, Jie ^{[1
]}

Li, Dan ^{[1
]}

机构：

[1] Shantou Univ, Dept Chem, Shantou 515063, Guangdong, Peoples R China

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2012年 / 134卷 / 01期

基金：

中国国家自然科学基金;

关键词：

ZEOLITIC-IMIDAZOLATE FRAMEWORKS; CARBON-DIOXIDE; THERMAL-STABILITY; CRYSTALS; TOPOLOGIES; CHEMISTRY; GERMANIUM; POLYMERS; CAPTURE; SURFACE;

D O I：

10.1021/ja208469n

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The gyroid is ubiquitous for underlying the construction of natural substance and artificial zeolites, but it has been, surprisingly, overlooked by chemists who work in the field of metal-organic frameworks (MOFs). In this work, a series of gyroidal MOFs with gie topology, constructed from 1,2-bis((5H-imidazol-4-yl)methylene)hydrazine and octahedral metal ions, such as Zn-II, Mn-II, Cu-II, and Ni-II, have been synthesized. The Zn-II analogue, named as STU-1, shows exceptional thermal and chemical stabilities, and exhibits permanent porosity and CO2 capture ability.

引用

页码：67 / 70

页数：4

共 26 条

[1] Underlying nets in three-periodic coordination polymers: topology, taxonomy and prediction from a computer-aided analysis of the Cambridge Structural Database [J].

Alexandrov, E. V. ;

Blatov, V. A. ;

Kochetkov, A. V. ;

Proserpio, D. M. .

CRYSTENGCOMM, 2011, 13 (12) :3947-3958

[2] MINIMAL-SURFACES AND STRUCTURES - FROM INORGANIC AND METAL CRYSTALS TO CELL-MEMBRANES AND BIO-POLYMERS [J].

ANDERSSON, S ;

HYDE, ST ;

LARSSON, K ;

LIDIN, S .

CHEMICAL REVIEWS, 1988, 88 (01) :221-242

[3]

[Anonymous], 1997, FLATLAND GEOMETRIC F, DOI DOI 10.1016/B978-044481538-5/50005-8

[4] Mesostructured germanium with cubic pore symmetry [J].

Armatas, Gerasimos S. ;

Kanatzidis, Mercouri G. .

NATURE, 2006, 441 (7097) :1122-1125

[5] Effect of Pore Topology and Accessibility on Gas Adsorption Capacity in Zeolitic-Imidazolate Frameworks: Bringing Molecular Simulation Close to Experiment [J].

Babarao, Ravichandar ;

Dai, Sheng ;

Jiang, De-en .

JOURNAL OF PHYSICAL CHEMISTRY C, 2011, 115 (16) :8126-8135

[6] High-throughput synthesis of zeolitic imidazolate frameworks and application to CO2 capture [J].

Banerjee, Rahul ;

Phan, Anh ;

Wang, Bo ;

Knobler, Carolyn ;

Furukawa, Hiroyasu ;

O'Keeffe, Michael ;

Yaghi, Omar M. .

SCIENCE, 2008, 319 (5865) :939-943

[7] Highly efficient separation of carbon dioxide by a metal-organic framework replete with open metal sites [J].

Britt, David ;

Furukawa, Hiroyasu ;

Wang, Bo ;

Glover, T. Grant ;

Yaghi, Omar M. .

PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 2009, 106 (49) :20637-20640

[8] Interwoven metal-organic framework on a periodic minimal surface with extra-large pores [J].

Chen, BL ;

Eddaoudi, M ;

Hyde, ST ;

O'Keeffe, M ;

Yaghi, OM .

SCIENCE, 2001, 291 (5506) :1021-1023

[9] What do we know about three-periodic nets? [J].

Delgado-Friedrichs, O ;

Foster, MD ;

O'Keeffe, M ;

Proserpio, DM ;

Treacy, MMJ ;

Yaghi, OM .

JOURNAL OF SOLID STATE CHEMISTRY, 2005, 178 (08) :2533-2554

[10] Synthesis and organization of zeolite-like materials with three-dimensional helical pores [J].

Gier, TE ;

Bu, XH ;

Feng, PY ;

Stucky, GD .

NATURE, 1998, 395 (6698) :154-157

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