Solvothermal synthesis, structure and properties of a new 3-D Cu(I)-Gd(III) heterometallic coordination framework

被引：8

作者：

Chen, Man-Sheng ^{[1
]}

Deng, Yi-Fang ^{[1
]}

Zhang, Chun-Hua ^{[1
]}

Kuang, Dai-Zhi ^{[1
]}

Nie, Xue ^{[1
]}

Liu, Yang ^{[1
]}

机构：

[1] Hengyang Normal Univ, Dept Chem & Mat Sci, Hengyang 421008, Peoples R China

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2011年 / 14卷 / 06期

关键词：

Heterometallic complex; Metal-organic framework; Solvothermal reaction; Magnetism; METAL-ORGANIC FRAMEWORKS; LN-AG LN; MAGNETIC-PROPERTIES; MOLECULAR-STRUCTURE; CRYSTAL-STRUCTURE; N-DONOR; POLYMERS; 3D; COMPLEXES; EU;

D O I：

10.1016/j.inoche.2011.03.038

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new 3d-4f heterometallic coordination polymer, [CuGd2(INAIP)(3)(HCOO)(H2O)(3)center dot 3H(2)O (1), [H(2)INAIP = 5-(isonicotinamido)isophthalic acid] has been synthesized and characterized by single crystal X-ray diffraction analysis. The results of structural analyses show that 1 has a two-fold interpenetrated 3D coordination framework with a rare sqc27 topology. In addition, thermogravimetric and magnetic properties were also investigated. (C) 2011 Elsevier B.V. All rights reserved.

引用

页码：944 / 947

页数：4

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