Iridium corroles

被引：111

作者：

Palmer, Joshua H. ^{[2
]}

Day, Michael W. ^{[2
]}

Wilson, Aaron D. ^{[2
]}

Henling, Lawrence M. ^{[2
]}

Gross, Zeev ^{[1
]}

Gray, Harry B. ^{[2
]}

机构：

[1] Technion Israel Inst Technol, Schulich Dept Chem, IL-32000 Haifa, Israel

[2] CALTECH, Beckman Inst, Pasadena, CA 91125 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2008年 / 130卷 / 25期

关键词：

D O I：

10.1021/ja801049t

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

This work reports the synthesis and full characterization of 5,10,15-tris-pentafluorophenylcorrolato-iridium(III) bis-trimethylamine 1 and its octabromo derivative 2. The corrole is planar in both cases (the mean deviation from the plane is as low as 0.0371 angstrom for 1 and 0.0325 angstrom for 2), the UV-vis spectra display a split Soret band with a shoulder attributable to an MLCT transition, and cyclic voltammetry reveals that the iridium(l]) oxidation state cannot be accessed, while the oxidation to formal iridium(IV) complexes is achieved at much lower potentials than in other coordination environments.

引用

页码：7786 / +

页数：3

共 35 条

[21] Synthesis and full characterization of molybdenum and antimony corroles and utilization of the latter complexes as very efficient catalysts for highly selective aerobic oxygenation reactions [J].

Luobeznova, I ;

Raizman, M ;

Goldberg, I ;

Gross, Z .

INORGANIC CHEMISTRY, 2006, 45 (01) :386-394

[22] Aerobic oxidations catalyzed by chromium corroles [J].

Mahammed, A ;

Gray, HB ;

Meier-Callahan, AE ;

Gross, Z .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (05) :1162-1163

[23] Cyclometalated iridium(III) aquo complexes: Efficient and tunable catalysts for the homogeneous oxidation of water [J].

McDaniel, Neal D. ;

Coughlin, Frederick J. ;

Tinker, Leonard L. ;

Bernhard, Stefan .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (01) :210-217

[24] Novel aspects of corrole chemistry [J].

Nardis, S ;

Monti, D ;

Paolesse, R .

MINI-REVIEWS IN ORGANIC CHEMISTRY, 2005, 2 (04) :355-372

[25] Manganese(III) and manganese(IV) corroles: synthesis', spectroscopic, electrochemical and X-ray structural characterization [J].

Ou, ZP ;

Erben, C ;

Autret, M ;

Will, S ;

Rosen, D ;

Lex, J ;

Vogel, E ;

Kadish, KM .

JOURNAL OF PORPHYRINS AND PHTHALOCYANINES, 2005, 9 (06) :398-412

[26] β-pyrrole brominated meso-tetraphenylporphyrins:: synthesis, spectral and electrochemical properties [J].

Ou, ZP ;

Shao, JG ;

D'Souza, F ;

Tagliatesta, P ;

Kadish, KM .

JOURNAL OF PORPHYRINS AND PHTHALOCYANINES, 2004, 8 (1-3) :201-214

[27] Synthesis and functionalization of meso-aryl-substituted corroles [J].

Paolesse, R ;

Nardis, S ;

Sagone, F ;

Khoury, RG .

JOURNAL OF ORGANIC CHEMISTRY, 2001, 66 (02) :550-556

[28] Synthesis, spectroscopy, and structures of new rhodium(I) and rhodium(III) corroles and catalysis thereby [J].

Saltsman, I ;

Simkhovich, L ;

Balazs, Y ;

Goldberg, I ;

Gross, Z .

INORGANICA CHIMICA ACTA, 2004, 357 (10) :3038-3046

[29] Mono- and binuclear ruthenium corroles: Synthesis, spectroscopy, electrochemistry, and structural characterization [J].

Simkhovich, L ;

Luobeznova, I ;

Goldberg, I ;

Gross, Z .

CHEMISTRY-A EUROPEAN JOURNAL, 2003, 9 (01) :201-208

[30] Iron(IV) corroles are potent catalysts for aziridination of olefins by Chloramine-T [J].

Simkhovich, L ;

Gross, Z .

TETRAHEDRON LETTERS, 2001, 42 (45) :8089-8092

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