Iridium corroles

被引：111

作者：

Palmer, Joshua H. ^{[2
]}

Day, Michael W. ^{[2
]}

Wilson, Aaron D. ^{[2
]}

Henling, Lawrence M. ^{[2
]}

Gross, Zeev ^{[1
]}

Gray, Harry B. ^{[2
]}

机构：

[1] Technion Israel Inst Technol, Schulich Dept Chem, IL-32000 Haifa, Israel

[2] CALTECH, Beckman Inst, Pasadena, CA 91125 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2008年 / 130卷 / 25期

关键词：

D O I：

10.1021/ja801049t

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

This work reports the synthesis and full characterization of 5,10,15-tris-pentafluorophenylcorrolato-iridium(III) bis-trimethylamine 1 and its octabromo derivative 2. The corrole is planar in both cases (the mean deviation from the plane is as low as 0.0371 angstrom for 1 and 0.0325 angstrom for 2), the UV-vis spectra display a split Soret band with a shoulder attributable to an MLCT transition, and cyclic voltammetry reveals that the iridium(l]) oxidation state cannot be accessed, while the oxidation to formal iridium(IV) complexes is achieved at much lower potentials than in other coordination environments.

引用

页码：7786 / +

页数：3

共 35 条

[1] Corrole-based applications [J].

Aviv, Iris ;

Gross, Zeev .

CHEMICAL COMMUNICATIONS, 2007, (20) :1987-1999

[2] Synthesis and structure of [meso-triarylcorrolato]silver(III) [J].

Brückner, C ;

Barta, CA ;

Briñas, RP ;

Bauer, JAK .

INORGANIC CHEMISTRY, 2003, 42 (05) :1673-1680

[3] Synthesis and characterization of the nitrides of platinum and iridium [J].

Crowhurst, JC ;

Goncharov, AF ;

Sadigh, B ;

Evans, CL ;

Morrall, PG ;

Ferreira, JL ;

Nelson, AJ .

SCIENCE, 2006, 311 (5765) :1275-1278

[4] Paramagnetic (alkene)Rh and (alkene)Ir complexes: Metal or ligand radicals? [J].

de Bruin, Bas ;

Hetterscheid, Dennis G. H. .

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2007, (02) :211-230

[5] DNA binding and catalytic properties of positively charged corroles [J].

Gershman, Zoya ;

Goldberg, Israel ;

Gross, Zeev .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2007, 46 (23) :4320-4324

[6] Nitrogen atom transfer between manganese complexes of salen, porphyrin, and corrole and characterization of a (nitrido)manganese(VI) corrole [J].

Golubkov, G ;

Gross, Z .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (10) :3258-3259

[7] Chromium(V) and chromium(VI) nitrido complexes of tris(pentafluorophenyl)corrole [J].

Golubkov, G ;

Gross, Z .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2003, 42 (37) :4507-4510

[8]

Golubkov G, 2001, ANGEW CHEM INT EDIT, V40, P2132, DOI 10.1002/1521-3773(20010601)40:11<2132::AID-ANIE2132>3.0.CO

[9]

2-5

[10] Reduction of cobalt and iron corroles and catalyzed reduction of CO2 [J].

Grodkowski, J ;

Neta, P ;

Fujita, E ;

Mahammed, A ;

Simkhovich, L ;

Gross, Z .

JOURNAL OF PHYSICAL CHEMISTRY A, 2002, 106 (18) :4772-4778

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