Iridium corroles

被引：110

作者：

Palmer, Joshua H. ^{[2
]}

Day, Michael W. ^{[2
]}

Wilson, Aaron D. ^{[2
]}

Henling, Lawrence M. ^{[2
]}

Gross, Zeev ^{[1
]}

Gray, Harry B. ^{[2
]}

机构：

[1] Technion Israel Inst Technol, Schulich Dept Chem, IL-32000 Haifa, Israel

[2] CALTECH, Beckman Inst, Pasadena, CA 91125 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2008年 / 130卷 / 25期

关键词：

D O I：

10.1021/ja801049t

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

This work reports the synthesis and full characterization of 5,10,15-tris-pentafluorophenylcorrolato-iridium(III) bis-trimethylamine 1 and its octabromo derivative 2. The corrole is planar in both cases (the mean deviation from the plane is as low as 0.0371 angstrom for 1 and 0.0325 angstrom for 2), the UV-vis spectra display a split Soret band with a shoulder attributable to an MLCT transition, and cyclic voltammetry reveals that the iridium(l]) oxidation state cannot be accessed, while the oxidation to formal iridium(IV) complexes is achieved at much lower potentials than in other coordination environments.

引用

页码：7786 / +

页数：3

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