A Dimer of Silaisonitrile with Two-Coordinate Silicon Atoms

被引：73

作者：

Ghadwal, Rajendra S. ^{[1
]}

Roesky, Herbert W. ^{[1
]}

Proepper, Kevin ^{[1
]}

Dittrich, Birger ^{[1
]}

Klein, Susanne ^{[2
]}

Frenking, Gernot ^{[2
]}

机构：

[1] Univ Gottingen, Inst Anorgan Chem, D-37077 Gottingen, Germany

[2] Univ Marburg, Fachbereich Chem, D-35032 Marburg, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2011年 / 50卷 / 23期

关键词：

density functional calculations; main-group elements; multiple bonds; silylenes; X-ray diffraction; N-HETEROCYCLIC CARBENES; OLEFIN-METATHESIS CATALYSTS; MAIN-GROUP ELEMENTS; DOUBLE-BOND; NOBEL LECTURE; MULTIPLE BONDS; STABILITIES; COMPOUND; DICHLOROSILYLENE; COORDINATION;

D O I：

10.1002/anie.201101320

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A specialty of silicon: A stable dimeric silaisonitrile (ArNSi:) 2 (see picture; Ar=2,6-bis(2,4,6-triisopropylphenyl)phenyl) was prepared by the reduction of dichlorosilaimine IPrCl2SiNAr with KC8. The dimer is the first base-free disilylene with two-coordinate silicon atoms; reaction with trimethylsilyl azide affords the first bis(silaimine) (ArNSiNSiMe3)2 with three-coordinate silicon atoms. © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：5374 / 5378

页数：5

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