Study on new quinacridone derivatives with enhanced third-order nonlinear optical properties

被引：8

作者：

Cui, Yanhong ^{[1
]}

Liang, Guanqiu ^{[1
]}

Jia, Jianhong ^{[1
]}

Yu, Guoyi ^{[1
]}

Sha, Yangcheng ^{[1
]}

Zhou, Chunsong ^{[1
]}

She, Yuanbin ^{[1
]}

机构：

[1] Zhejiang Univ Technol, Coll Chem Engn, Hangzhou 310032, Peoples R China

来源：

TETRAHEDRON | 2020年 / 76卷 / 22期

基金：

中国国家自然科学基金;

关键词：

Second-order hyperpolarizability; Quinacridone derivatives; NLO materials; Z-scan technology; NLO PROPERTIES; FILM TRANSISTORS; POLYMERS; DYES; DFT; SUSCEPTIBILITY; CHROMOPHORES; GRAPHENE; ZINDO/S;

D O I：

10.1016/j.tet.2020.131169

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Seven new quinacridone derivatives were designed and synthesized. The relationship between molecular structure and nonlinear optical properties was studied by cyclic voltammetry, DFT calculation and Z-scan. By introducing strong electron donating groups at the two sides of the quinacridone, and then introducing a strong electron withdrawing group dicyanoethylene group, the band gap of the molecule can be effectively reduced, and the intramolecular charge transfer can be promoted. The results shown that the HOMO/LUMO band gaps of the target compounds are all reduced, and QA-F has the best third- order nonlinear optical performance, and its gamma (gamma = 5.32 x 10(-33) esu) is 4.38 times that of QA-1 (gamma = 1.21 x 10(-33) esu). (C) 2020 Elsevier Ltd. All rights reserved.

引用

页数：13

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