A new cadmium(ii) coordination polymer with 1,4-cyclohexanedicarboxylate acid and phenanthroline derivate: Synthesis and crystal structure

被引：5

作者：

Su, Beihao ^{[1
,2
]}

Shi, Yihan ^{[2
]}

Peng, Xuehan ^{[2
]}

Kong, Zhiguo ^{[1
,2
]}

Chang, Limin ^{[1
,2
]}

机构：

[1] Jilin Normal Univ, Key Lab Preparat & Applicat Environm Friendly Mat, Minist Educ, Changchun 130103, Peoples R China

[2] Jilin Normal Univ, Dept Chem, Siping 136000, Peoples R China

来源：

MAIN GROUP METAL CHEMISTRY | 2022年 / 45卷 / 01期

关键词：

Cd(ii); coordination polymer; phenanthroline derivate; crystal structure; COMPLEXES;

D O I：

10.1515/mgmc-2022-0020

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new Cd(ii) coordination polymers, formulated as [Cd(1,4-chdc)(L)]( n ) (1) (L = 1-(1H-imidazo[4,5-f][1,10]phenanthrolin-2-yl)naphthalen-2-ol ligands and 1,4-H(2)chdc = 1,4-cyclohexanedicarboxylate acid), were successfully synthesized by using L ligand and 1,4-H(2)chdc acid under hydrothermal conditions and characterized by single crystal X-ray elemental analyses, diffraction, and IR spectroscopy. Each Cd(ii) atom is a distorted pentagonal bipyramidal geometry connecting the deprotonated 1,4-chdc anion to form a 2D layer, and a 2D layer is formed into a 3D supramolecular structure by the pi-pi stacking interactions between neighboring layers.

引用

页码：208 / 212

页数：5

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