Elaboration and characterization of organic/inorganic hybrid nanoporous material incorporating Keggin-type Mo-Si polyanions

被引：5

作者：

Dizhbite, T. ^{[1
]}

Mironova-Ulmane, N. ^{[2
]}

Volperts, A.

Andersone, A. ^{[1
]}

Jashina, L. ^{[1
]}

Kaerner, T. ^{[3
]}

Telysheva, G. ^{[1
]}

机构：

[1] Latvian State Inst Wood Chem, Riga, Latvia

[2] Univ Latvia, Inst Solid State Phys, Riga, Latvia

[3] Univ Tartu, Inst Phys, Tartu, Estonia

来源：

FUNCTIONAL MATERIALS AND NANOTECHNOLOGIES : FM&NT-2007 | 2007年 / 93卷

关键词：

D O I：

10.1088/1742-6596/93/1/012011

中图分类号：

TB3 [工程材料学];

学科分类号：

0805 ; 080502 ;

摘要：

A novel nanoporous (pore size of 11 nm in average, BET surface area of 30 m(2)/g, pore volume of 300 mm(3)/g) hybrid inorganic-organic material was synthesized using the solid-phase interaction at room temperature of plant-originated phenylpropanoid polymer lignin and a Keggin-type heteropolyanion [SiMo12O40](4-). The partly reduction of Mo(VI) to Mo(V) and complexes formation between lignin and polyanion have been established by EPR, FT-IR and Raman spectroscopy. The XRD pattern and FT-IR spectrum of the hybrid material and indicates that [SiMo12O40](4-) anion maintains the Keggin structure.

引用

页数：6

共 17 条

[1] ESR STUDIES OF THIN AMORPHOUS FILMS OF MOO3-EFFECTS OF SUBSTRATE-TEMPERATURE, FILM THICKNESS AND ANNEALING PROCEDURES [J].