Selective and efficient oxidation of sulfides to sulfoxides with N-bromosuccinimide in the presence of β-cyclodextrin in water

被引：89

作者：

Surendra, K ^{[1
]}

Krishnaveni, NS ^{[1
]}

Kumar, VP ^{[1
]}

Sridhar, R ^{[1
]}

Rao, KR ^{[1
]}

机构：

[1] Indian Inst Chem Technol, Div Organ Chem 1, Hyderabad 500007, Andhra Pradesh, India

来源：

TETRAHEDRON LETTERS | 2005年 / 46卷 / 27期

关键词：

sulfides; sulfoxides; oxidation; N-bromosuccinimide; beta-cyclodextrin; biomimetic; water;

D O I：

10.1016/j.tetlet.2005.05.011

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A simple and highly selective oxidation of sulfides to sulfoxides with N-bromosuccinimide (NBS) catalyzed by beta-cyclodextrin in water has been developed. A series Of Sulfides were oxidized selectively at room temperature in excellent yields. This reaction proceeds without over-oxidation to sulfones under mild conditions using water as a solvent and has many advantages over the existing methodologies. (c) 2005 Published by Elsevier Ltd.

引用

页码：4581 / 4583

页数：3

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