Selective and efficient oxidation of sulfides to sulfoxides with N-bromosuccinimide in the presence of β-cyclodextrin in water

被引：89
|
作者：
Surendra, K [1 ]
Krishnaveni, NS [1 ]
Kumar, VP [1 ]
Sridhar, R [1 ]
Rao, KR [1 ]
机构：
[1] Indian Inst Chem Technol, Div Organ Chem 1, Hyderabad 500007, Andhra Pradesh, India
来源：
TETRAHEDRON LETTERS | 2005年 / 46卷 / 27期
关键词：
sulfides; sulfoxides; oxidation; N-bromosuccinimide; beta-cyclodextrin; biomimetic; water;
D O I：
10.1016/j.tetlet.2005.05.011
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A simple and highly selective oxidation of sulfides to sulfoxides with N-bromosuccinimide (NBS) catalyzed by beta-cyclodextrin in water has been developed. A series Of Sulfides were oxidized selectively at room temperature in excellent yields. This reaction proceeds without over-oxidation to sulfones under mild conditions using water as a solvent and has many advantages over the existing methodologies. (c) 2005 Published by Elsevier Ltd.
引用
收藏
页码：4581 / 4583
页数：3
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