Poly(sulfosalicylic acid)-functionalized gold nanoparticles for the detection of tetrabromobisphenol A at pM concentrations

Developing a sensitive, simple and fast sensing system for 3,3',5,5'-tetrabromobisphenol A (TBBPA) is important because of its ubiquitousness and high toxicity. In this work, a gold nanoparticles (AuNPs) and poly(sulfosalicylic acid) (PSSA) composite film (AuNPs-PSSA) is fabricated in-situ on an electrode surface via cyclic voltammetry scanning. The characterization via scanning electron microscopy (SEM), atomic force microscopy (AFM), energy dispersive X-ray (EDX) analysis and Fourier transform infrared (FTIR) spectroscopy indicate that the PSSA film is homogeneously decorated with AuNPs, and a highly uniform and thin composite film is obtained. Electrochemical tests reveal that the AuNPs-PSSA film exhibits larger active surface area, lower charge transfer resistance and higher accumulation efficiency toward TBBPA than single AuNPs and PSSA film. As a result, the oxidation signals and sensing sensitivity of TBBPA are significantly enhanced on the surface of the AuNPs-PSSA. The developed TBBPA sensing platform using AuNPs-PSSA composite film, with low detection limit (25 pM) and wide linear range (0.1 -10 nM), is successfully utilized to measure TBBPA level in wastewater samples. The results are highly consistent with those that obtained from high-performance liquid chromatography. The preparation and reusability of the TBBPA sensor can be automatically achieved through CV scanning, providing a promising on-line monitoring system for wastewater samples.