Monitoring of Liquid-Phase Organic Reactions by Photoelectron Spectroscopy

被引：23
作者：
Kolbeck, Claudia [1 ]
Niedermaier, Inga [1 ]
Taccardi, Nicola [2 ]
Schulz, Peter S. [2 ]
Maier, Florian [1 ]
Wasserscheid, Peter [2 ]
Steinrueck, Hans-Peter [1 ]
机构：
[1] Univ Erlangen Nurnberg, Lehrstuhl Phys Chem 2, D-91058 Erlangen, Germany
[2] Univ Erlangen Nurnberg, Lehrstuhl Chem Reakt Tech, D-91058 Erlangen, Germany
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2012年 / 51卷 / 11期
关键词：
ionic liquids; reaction monitoring; surface chemistry; X-ray photoelectron spectroscopy; zwitterions; IONIC LIQUIDS; MODEL CATALYSIS;
D O I：
10.1002/anie.201107402
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
There are strings attached: After linking the reacting groups to head groups of ionic liquids to drastically lower the vapour pressures of the reactants, ordinary liquid-phase organic reactions can be monitored by in situ X-ray photoelectron spectroscopy. This approach is demonstrated for the nucleophilic substitution of an alkyl amine and an alkyl chloride moiety, which are attached to the cation and anion of ionic liquids, respectively. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码：2610 / 2613
页数：4
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