Monitoring of Liquid-Phase Organic Reactions by Photoelectron Spectroscopy

被引：23
作者：
Kolbeck, Claudia [1 ]
Niedermaier, Inga [1 ]
Taccardi, Nicola [2 ]
Schulz, Peter S. [2 ]
Maier, Florian [1 ]
Wasserscheid, Peter [2 ]
Steinrueck, Hans-Peter [1 ]
机构：
[1] Univ Erlangen Nurnberg, Lehrstuhl Phys Chem 2, D-91058 Erlangen, Germany
[2] Univ Erlangen Nurnberg, Lehrstuhl Chem Reakt Tech, D-91058 Erlangen, Germany
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2012年 / 51卷 / 11期
关键词：
ionic liquids; reaction monitoring; surface chemistry; X-ray photoelectron spectroscopy; zwitterions; IONIC LIQUIDS; MODEL CATALYSIS;
D O I：
10.1002/anie.201107402
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
There are strings attached: After linking the reacting groups to head groups of ionic liquids to drastically lower the vapour pressures of the reactants, ordinary liquid-phase organic reactions can be monitored by in situ X-ray photoelectron spectroscopy. This approach is demonstrated for the nucleophilic substitution of an alkyl amine and an alkyl chloride moiety, which are attached to the cation and anion of ionic liquids, respectively. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码：2610 / 2613
页数：4
相关论文
共 50 条
  • [1] In Situ XPS Monitoring of Bulk Ionic Liquid Reactions: Shedding Light on Organic Reaction Mechanisms
    Licence, Peter
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2012, 51 (20) : 4789 - 4791
  • [2] Metal applications of liquid-phase microextraction
    Angel Aguirre, Miguel
    Baile, Paola
    Vidal, Lorena
    Canals, Antonio
    TRAC-TRENDS IN ANALYTICAL CHEMISTRY, 2019, 112 : 241 - 247
  • [3] Pharmaceutical applications of liquid-phase microextraction
    Seidi, Shahram
    Rezazadeh, Maryam
    Yamini, Yadollah
    TRAC-TRENDS IN ANALYTICAL CHEMISTRY, 2018, 108 : 296 - 305
  • [4] Photoelectron spectroscopy on ionic liquid surfaces - Theory and experiment
    Ulbrich, Angela
    Reinmoeller, Markus
    Beenken, Wichard J. D.
    Krischok, Stefan
    JOURNAL OF MOLECULAR LIQUIDS, 2014, 192 : 77 - 86
  • [5] Stability of supported ionic liquid membranes as studied by X-ray photoelectron spectroscopy
    Fortunato, R
    Afonso, CAM
    Benavente, J
    Rodriguez-Castellón, E
    Crespo, JG
    JOURNAL OF MEMBRANE SCIENCE, 2005, 256 (1-2) : 216 - 223
  • [6] Probing a Gas/Liquid Acid-Base Reaction by X-ray Photoelectron Spectroscopy
    Niedermaier, Inga
    Taccardi, Nicola
    Wasserscheid, Peter
    Maier, Florian
    Steinrueck, Hans-Peter
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2013, 52 (34) : 8904 - 8907
  • [7] A study on the liquid-phase oxidation of toluene in ionic liquids
    Meng, Yan
    Liang, Bin
    Tang, Shengwei
    APPLIED CATALYSIS A-GENERAL, 2012, 439 : 1 - 7
  • [8] Recent developments in liquid-phase synthesis and applications of nanomagnesia
    Abdollahzade, Hanie
    Zamani, Asghar
    ADVANCES IN NANO RESEARCH, 2023, 14 (01) : 103 - 115
  • [9] 31P Nuclear Magnetic Resonance Spectroscopy for Monitoring Organic Reactions and Organic Compounds
    Anghinoni, Joao Marcos
    Rashid, Haroon Ur
    Lenardao, Eder Joao
    Silva, Marcio Santos
    CHEMICAL RECORD, 2024,
  • [10] Polyoxometalate-based phase transfer catalysis for liquid-solid organic reactions: a review
    Zhou, Yu
    Guo, Zengjing
    Hou, Wei
    Wang, Qian
    Wang, Jun
    CATALYSIS SCIENCE & TECHNOLOGY, 2015, 5 (09) : 4324 - 4335
12345