Conformational fingerprints in the IR and Raman spectra of oligoanilines: A combined theoretical and experimental study

被引：13

作者：

Choi, CH

Kertesz, M ^{[1
]}

Boyer, MI

Cochet, M

Quillard, S

Louarn, G

Lefrant, S

机构：

[1] Georgetown Univ, Dept Chem, Washington, DC 20057 USA

[2] Inst Mat Nantes, Lab Phys Cristalline, F-44322 Nantes 3, France

来源：

CHEMISTRY OF MATERIALS | 1999年 / 11卷 / 04期

关键词：

D O I：

10.1021/cm981022b

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Conformation sensitive bands are found in the sub-800-cm(-1) region of the IR and Raman spectra of an imine-type oligoaniline, 1. This allows the determination of the conformation in the powder sample (obtained by the Zaghal-Shatnawi procedure) to be predominantly nonplanar E; the abundance of the Z conformer with similar energy is about 5%.

引用

页码：855 / +

页数：4

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