Design and Self-Assembly of Macrocycles with Metals at the Corners Based on Dissymmetric Terpyridine Ligands

被引：4

作者：

Xu, Yaping ^{[1
]}

Su, Haoyue ^{[1
]}

Bai, Qixia ^{[2
]}

Fang, Fang ^{[3
]}

Ma, Jianjun ^{[1
]}

Zhang, Zhe ^{[2
]}

Hao, Xin-Qi ^{[4
,5
]}

Shi, Junjuan ^{[1
]}

Wang, Pingshan ^{[2
]}

Wang, Ming ^{[1
]}

机构：

[1] Jilin Univ, Coll Chem, State Key Lab Supramol Struct & Mat, Changchun 130012, Jilin, Peoples R China

[2] Guangzhou Univ, Inst Environm Res Greater Bay Area, Key Lab Water Qual & Conservat Pearl River Delta, Minist Educ, Guangzhou 510006, Guangdong, Peoples R China

[3] Shenzhen Univ, Instrumental Anal Ctr, Shenzhen 518055, Guangdong, Peoples R China

[4] Zhengzhou Univ, Coll Chem, Zhengzhou 450001, Henan, Peoples R China

[5] Zhengzhou Univ, Green Catalysis Ctr, Zhengzhou 450001, Henan, Peoples R China

来源：

CHEMISTRY-AN ASIAN JOURNAL | 2022年 / 17卷 / 07期

基金：

中国国家自然科学基金;

关键词：

Self-assembly; Metallo-supramolecule; Terpyridine; Macrocycle; SUPRAMOLECULAR CHEMISTRY; COMPLEXES; DISCRETE; ARCHITECTURES; CONSTRUCTION; POLYHEDRA;

D O I：

10.1002/asia.202200071

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Terpyridine-based discrete supramolecular architectures with metal ions at the corners have rarely been reported. Herein, we report two dissymmetric terpyridyl ligands LA and LB decorated at the 5-position and 4-position of terpyridine respectively. The complexes constructed by the self-assembly of LA and LB with Zn(II) exhibit hand-circle-like structures. Moreover, all Zn(II) are successfully fixed in the corners. A series of dimeric to hexameric macrocycles is obtained by head-to-tail connections with changing concentration. This work will pave the way for preparation of more elaborate self-assembled structures based on dissymetric ligands.

引用

页数：5

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