A New Carboxylate Selective Anion Receptor Utilizing Amide and Carbamate Hydrogens

被引:2
作者
Lee, Sung Kyu [1 ]
Kang, Jongmin [1 ]
机构
[1] Sejong Univ, Inst Biol Chem, Dept Chem, Seoul 143747, South Korea
基金
新加坡国家研究基金会;
关键词
Anion receptor; Amide; Carbamate; Hydrogen bonds; Anthracene; CHARGE NEUTRAL THIOUREA; BINDING-SITES; AMINO-ACIDS; CHOLIC-ACID; MOLECULAR RECOGNITION; FLUORESCENT SENSORS; BIS-CARBOXYLATES; PROTON-TRANSFER; PET SENSORS; UREA;
D O I
10.5012/bkcs.2011.32.9.3215
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A new anion receptor utilizing carbamate functionality as hydrogen bonding site has been designed and synthesized. This new receptor 2 has two amide hydrogens and two carbamate hydrogens anchored at 1,8-position of anthracene. These four hydrogens form a concave structure for the anions and the receptor 2 was found to be a selective receptor for acetate among the anions investigated.
引用
收藏
页码:3215 / 3218
页数:4
相关论文
共 55 条
[51]   Polyamine-based anion receptors:: Extraction and structural studies [J].
Wichmann, Kathrin ;
Antonioli, Bianca ;
Soehnel, Tilo ;
Wenzel, Marco ;
Gloe, Kerstin ;
Gloe, Karsten ;
Price, Jason R. ;
Lindoy, Leonard F. ;
Blake, Alexander J. ;
Schroeder, Martin .
COORDINATION CHEMISTRY REVIEWS, 2006, 250 (23-24) :2987-3003
[52]   Facile synthesis of oligophenylene-substituted calix[4]arenes and their enhanced binding properties [J].
Wong, MS ;
Xia, PF ;
Zhang, XL ;
Lo, PK ;
Cheng, YK ;
Yeung, KT ;
Guo, XL ;
Shuang, SM .
JOURNAL OF ORGANIC CHEMISTRY, 2005, 70 (07) :2816-2819
[53]   Cooperative metal-coordination and ion pairing in tripeptide recognition [J].
Wright, AT ;
Anslyn, EV .
ORGANIC LETTERS, 2004, 6 (09) :1341-1344
[54]   Study on host-guest complexation of anions based on tri-podal naphthylthiourea derivatives [J].
Xie, HZ ;
Yi, S ;
Wu, SK .
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1999, (12) :2751-2754
[55]   Imidazolium receptors for the recognition of anions [J].
Yoon, J ;
Kim, SK ;
Singh, NJ ;
Kim, KS .
CHEMICAL SOCIETY REVIEWS, 2006, 35 (04) :355-360