A New Carboxylate Selective Anion Receptor Utilizing Amide and Carbamate Hydrogens

被引:2
作者
Lee, Sung Kyu [1 ]
Kang, Jongmin [1 ]
机构
[1] Sejong Univ, Inst Biol Chem, Dept Chem, Seoul 143747, South Korea
基金
新加坡国家研究基金会;
关键词
Anion receptor; Amide; Carbamate; Hydrogen bonds; Anthracene; CHARGE NEUTRAL THIOUREA; BINDING-SITES; AMINO-ACIDS; CHOLIC-ACID; MOLECULAR RECOGNITION; FLUORESCENT SENSORS; BIS-CARBOXYLATES; PROTON-TRANSFER; PET SENSORS; UREA;
D O I
10.5012/bkcs.2011.32.9.3215
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A new anion receptor utilizing carbamate functionality as hydrogen bonding site has been designed and synthesized. This new receptor 2 has two amide hydrogens and two carbamate hydrogens anchored at 1,8-position of anthracene. These four hydrogens form a concave structure for the anions and the receptor 2 was found to be a selective receptor for acetate among the anions investigated.
引用
收藏
页码:3215 / 3218
页数:4
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