Preparation of zinc oxide free, transparent rubber nanocomposites using a layered double hydroxide filler

被引：87

作者：

Das, Amit ^{[2
]}

Wang, De-Yi ^{[1
,2
]}

Leuteritz, Andreas ^{[2
]}

Subramaniam, Kalaivani ^{[2
]}

Greenwell, H. Chris ^{[3
]}

Wagenknecht, Udo ^{[2
]}

Heinrich, Gert ^{[2
]}

机构：

[1] Sichuan Univ, Coll Chem, Ctr Degradable & Flame Retardant Polymer Mat ERCE, State Key Lab Polymer Mat Engn, Chengdu 610064, Peoples R China

[2] Leibniz Inst Polymerforsch Dresden eV, D-01069 Dresden, Germany

[3] Univ Durham, Dept Earth Sci, Durham DH1 3HP, England

来源：

JOURNAL OF MATERIALS CHEMISTRY | 2011年 / 21卷 / 20期

关键词：

SULFUR VULCANIZATION; TUBE-MODEL; POLYMER NETWORKS; ELASTICITY; ELASTOMERS; FLOCCULATION; ACTIVATOR; ADHESION;

D O I：

10.1039/c0jm03784b

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A layered double hydroxide (LDH) mineral filler particle has been designed and employed in rubber vulcanization to prepare a more environmentally friendly rubber composite. The LDH delivers zinc ions in the vulcanization process as accelerators, stearate anions as activators and simultaneously the mineral sheets act as a nanofiller to reinforce the rubber matrix whilst totally replacing the separate zinc oxide (ZnO) and stearic acid conventionally used in the formulation of rubber. This method leads to a significant reduction (nearly 10 times) of the zinc level and yields excellent transparent properties in the final rubber product. The morphological characterization, rheometric curing behaviour, mechanical properties and uniaxial multi-hysteresis behaviours of the resultant rubber/LDH nanocomposite are studied in this paper.

引用

页码：7194 / 7200

页数：7

共 30 条

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[2]

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