Preparation of zinc oxide free, transparent rubber nanocomposites using a layered double hydroxide filler

被引：86
作者：
Das, Amit [2 ]
Wang, De-Yi [1 ,2 ]
Leuteritz, Andreas [2 ]
Subramaniam, Kalaivani [2 ]
Greenwell, H. Chris [3 ]
Wagenknecht, Udo [2 ]
Heinrich, Gert [2 ]
机构：
[1] Sichuan Univ, Coll Chem, Ctr Degradable & Flame Retardant Polymer Mat ERCE, State Key Lab Polymer Mat Engn, Chengdu 610064, Peoples R China
[2] Leibniz Inst Polymerforsch Dresden eV, D-01069 Dresden, Germany
[3] Univ Durham, Dept Earth Sci, Durham DH1 3HP, England
来源：
JOURNAL OF MATERIALS CHEMISTRY | 2011年 / 21卷 / 20期
关键词：
SULFUR VULCANIZATION; TUBE-MODEL; POLYMER NETWORKS; ELASTICITY; ELASTOMERS; FLOCCULATION; ACTIVATOR; ADHESION;
D O I：
10.1039/c0jm03784b
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
A layered double hydroxide (LDH) mineral filler particle has been designed and employed in rubber vulcanization to prepare a more environmentally friendly rubber composite. The LDH delivers zinc ions in the vulcanization process as accelerators, stearate anions as activators and simultaneously the mineral sheets act as a nanofiller to reinforce the rubber matrix whilst totally replacing the separate zinc oxide (ZnO) and stearic acid conventionally used in the formulation of rubber. This method leads to a significant reduction (nearly 10 times) of the zinc level and yields excellent transparent properties in the final rubber product. The morphological characterization, rheometric curing behaviour, mechanical properties and uniaxial multi-hysteresis behaviours of the resultant rubber/LDH nanocomposite are studied in this paper.
引用
收藏
页码：7194 / 7200
页数：7
相关论文
共 30 条
  • [1] [Anonymous], 2005, CONSTITUTIVE MODELS
  • [2] Chapman V, 1997, SAFE RUBBER CHEM RED
  • [3] Layered double hydroxide based polymer nanocomposites
    Costa, Francis Reny
    Saphiannikova, Marina
    Wagenknecht, Udo
    Heinrich, Gert
    [J]. WAX CRYSTAL CONTROL: NANOCOMPOSITES, STIMULI-RESPONSIVE POLYMERS, 2008, 210 (01): : 101 - 168
  • [4] Nanocomposites based on chloroprene rubber: Effect of chemical nature and organic modification of nanoclay on the vulcanizate properties
    Das, Amit
    Costa, Francis Reny
    Wagenknecht, Udo
    Heinrich, Gert
    [J]. EUROPEAN POLYMER JOURNAL, 2008, 44 (11) : 3456 - 3465
  • [5] A novel family of layered double hydroxides -: [MAl4(OH)12](NO3)2•xH2O (M = Co, Ni, Cu, Zn)
    Fogg, AM
    Williams, GR
    Chester, R
    O'Hare, D
    [J]. JOURNAL OF MATERIALS CHEMISTRY, 2004, 14 (15) : 2369 - 2371
  • [6] ZINC TOXICITY
    FOSMIRE, GJ
    [J]. AMERICAN JOURNAL OF CLINICAL NUTRITION, 1990, 51 (02) : 225 - 227
  • [7] On the application of computer simulation techniques to anionic and cationic clays: A materials chemistry perspective
    Greenwell, HC
    Jones, W
    Coveney, PV
    Stackhouse, S
    [J]. JOURNAL OF MATERIALS CHEMISTRY, 2006, 16 (08) : 708 - 723
  • [8] Effect of zinc complexes as activator for sulfur vulcanization in various rubbers
    Heideman, G
    Noordermeer, JWM
    Datta, RN
    van Baarle, B
    [J]. RUBBER CHEMISTRY AND TECHNOLOGY, 2005, 78 (02): : 245 - 257
  • [9] Zinc loaded clay as activator in sulfur vulcanization: A new route for zinc oxide reduction in rubber compounds
    Heideman, G
    Noordermeer, JWM
    Datta, RN
    [J]. RUBBER CHEMISTRY AND TECHNOLOGY, 2004, 77 (02): : 336 - 355
  • [10] Multifunctional additives as zinc-free curatives for sulfur vulcanization
    Heideman, Geert
    Noordermeer, Jacques W. M.
    Datta, Rabin N.
    [J]. RUBBER CHEMISTRY AND TECHNOLOGY, 2006, 79 (04): : 561 - 588
123