Radon distribution in a gasoline-contaminated aquifer

Naturally occurring radon-222 gas in groundwater was investigated as a partitioning tracer to detect non-aqueous phase liquid (NAPL) in a gasoline-contaminated aquifer. The radon-222 activity of groundwater decreased significantly from an average of 7.38 +/- 1.68 Bq L-1 measured in monitoring wells located upgradient in the uncontaminated zone to an average of 2.30 +/- 0.60 Bq L-1 measured in monitoring wells inside the NAPL source zone. Meanwhile, the radium-226 concentrations measured in aquifer matrix were virtually homogeneous at several locations both upgradient of and inside the NAPL source zone. Furthermore, the NAPL concentration obtained from the Radon Deficit Factor agrees reasonably with the results derived from direct sampling and chemical analysis of soil samples taken from the residual NAPL source zone. The field results of this study confirmed the general applicability of groundwater radon to detect residual NAPL source zone. (c) 2007 Elsevier Ltd. All rights reserved.