Regioselective benzoyloxylative dearomatization of naphthols by benzoyl peroxide under catalyst-free conditions

被引：0
|
作者：
Chen, Hong-Wei [1 ,2 ]
Song, Qin-Hua [1 ,2 ]
机构：
[1] Univ Sci & Technol China, Hefei Natl Lab Phys Sci Microscale, Hefei 230026, Peoples R China
[2] Univ Sci & Technol China, Dept Chem, Hefei 230026, Peoples R China
来源：
ORGANIC & BIOMOLECULAR CHEMISTRY | 2021年 / 19卷 / 33期
关键词：
ENANTIOSELECTIVE ALPHA-BENZOYLOXYLATION; HYDROXYLATIVE PHENOL DEAROMATIZATION; BETA-KETO-ESTERS; ASYMMETRIC DEAROMATIZATION; OXIDATIVE DEAROMATIZATION; ARYLATIVE DEAROMATIZATION; SPIROLACTONIZATION; DERIVATIVES; IRIDIUM; CONSTRUCTION;
D O I：
10.1039/d1ob01274f
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A direct regioselective benzoyloxylative dearomatization of both alpha- and beta-naphthols by benzoyl peroxide under an air atmosphere, and radical inhibitor- and catalyst-free conditions at room temperature is described. The methodology provides a new efficient strategy for the construction of alpha-ketol derivatives bearing an oxo-quaternary carbon center from naphthols with good to excellent yields.
引用
收藏
页码：7161 / 7164
页数：4
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