First synthesis of dialkyl phosphonate derivatives of sesquiterpene α-methylene-γ-lactone

被引：11

作者：

Jalmahanbetova, RI

Rakhimova, BB

Raldugin, VA

Bagryanskaya, IY

Gatilov, YV

Shakirov, MM

Kulyjasov, AT

Adekenov, SM

Tolstikov, GA

机构：

[1] Russian Acad Sci, NN Vorozhtsov Novosibirsk Inst Organ Chem, Siberian Branch, Novosibirsk 630090, Russia

[2] Minist Educ & Sci Republ Kazakhstan, Inst Phytochem, Karaganda 470032, Kazakhstan

来源：

RUSSIAN CHEMICAL BULLETIN | 2003年 / 52卷 / 03期

关键词：

sesquiterpene lactones; arglabin; guaianolide; dialkyl phosphonates; phosphonates; two-dimensional NMR spectroscopy; X-ray diffraction analysis;

D O I：

10.1023/A:1023943830932

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The stereoselective synthesis of two phosphorus-containing derivatives of the known guaianolide arglabin was carried out for the first time. The molecular structures of these products were established based on the spectroscopic data and the results of X-ray diffraction analysis of one of these compounds.

引用

页码：748 / 751

页数：4

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