Chiral phosphine-phosphoramidite ligands in asymmetric catalysis

被引：22

作者：

Chen, Xiu-Shuai ^{[1
,2
]}

Hou, Chuan-Jin ^{[1
,2
]}

Hu, Xiang-Ping ^{[2
]}

机构：

[1] Dalian Polytech Univ, Sch Light Ind & Chem Enginerring, Dalian 116034, Peoples R China

[2] Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China

来源：

SYNTHETIC COMMUNICATIONS | 2016年 / 46卷 / 11期

基金：

中国国家自然科学基金;

关键词：

Asymmetric catalysis; chiral ligand; hydroformylation; hydrogenation; phosphine-phosphoramidite; HIGHLY ENANTIOSELECTIVE HYDROGENATION; ROCHE ESTER; EFFICIENT; HYDROFORMYLATION; INDOLPHOS; DERIVATIVES; COMPLEXES; QUINAPHOS; VERSATILE; SYMMETRY;

D O I：

10.1080/00397911.2016.1171362

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Chiral phosphine-phosphoramidite ligands, featuring ready availability, easy modification, and stability towards air and moisture, have recently emerged as a new kind of robust ligands for asymmetric catalysis. They have been found to display wide utilities in various catalytic asymmetric reactions, giving excellent enantioselectivities in the Rh-, Ru-, and Ir-catalyzed asymmetric hydrogenation of C=C, C=O, and C=N double bonds; Rh-catalyzed asymmetric hydroformylation; Pd-catalyzed asymmetric hydrophosphorylation; Pd-catalyzed asymmetric allylic alkylation; Ag-catalyzed asymmetric [3 + 2] cycloaddition; and Cu-catalyzed conjugate addition and reduction. In this review, the progress on the development of chiral phosphine-phosphoramidite ligands in asymmetric catalysis has been summarized. [GRAPHICS] .

引用

页码：917 / 941

页数：25

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