Complexation of lead(II) by nicotinamide (nia):: Crystal structure of polymeric Pb(nia)(NO3)2

被引:19
|
作者
Najafpour, Mohammad Mahdi
Lis, Tadeusz
Holynska, Malgorzata
机构
[1] Dorna Inst Sci, Khozestan, Iran
[2] Univ Wroclaw, Fac Chem, PL-50383 Wroclaw, Poland
关键词
crystal structure; coordination polymer; nicotinamide; Pb(II) complex;
D O I
10.1016/j.ica.2007.04.012
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Lead(II) nitrate complex with nicotinamide has been synthesized and characterized by elemental analysis, IR, H-1 NMR, C-13 NMR, UV-Vis spectroscopy and X-ray crystallography. The Pb2+ centres linked through nicotinamide and nitrate(V) ligands form a two-dimensional polymeric structure defining a double layer and each layer is also stabilized by hydrogen bonds of N-H center dot center dot center dot O and C-H center dot center dot center dot O type. (C) 2007 Elsevier B.V. All rights reserved.
引用
收藏
页码:3452 / 3455
页数:4
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