Near-infrared fluorophores containing benzo[c]heterocycle subunits

被引:69
|
作者
Meek, Scott T. [1 ]
Nesterov, Evgueni E. [1 ]
Swager, Timothy M. [1 ]
机构
[1] MIT, Dept Chem, Cambridge, MA 02139 USA
关键词
D O I
10.1021/ol800988w
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
The syntheses and spectroscopic properties of eight new push-pull-type near-infrared fluorophores that contain either isobenzofuran or isothianaphthene subunits are presented. The isobenzofuran dyes demonstrate significantly red-shifted absorption compared with their isothianaphthene counterparts, which is attributed to isobenzofuran's more potent pro-quinoidal character.
引用
收藏
页码:2991 / 2993
页数:3
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