Mn(III)-Catalyzed Radical Reactions of 1,3-Dicarbonyl Compounds and Cyclopropanols with Vinyl Azides for Divergent Synthesis of Azaheterocycles

被引：38

作者：

Chiba, Shunsuke ^{[1
]}

机构：

[1] Nanyang Technol Univ, Sch Phys & Math Sci, Div Chem & Biol Chem, Singapore 637371, Singapore

来源：

CHIMIA | 2012年 / 66卷 / 06期

关键词：

Azaheterocycles; Cyclopropanols; 1,3-Dicarbonyl compounds; Manganese; Radicals; Vinyl azides; STRYCHNOS-MELINONIANA BAILLON; 1ST TOTAL-SYNTHESIS; MANGANESE(III) 2-PYRIDINECARBOXYLATE; GAMMA-LACTONES; ATOM ECONOMY; STEP ECONOMY; OXIDATION; PYRROLES; DERIVATIVES; GENERATION;

D O I：

10.2533/chimia.2012.377

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Mn(III)-catalyzed formal [3+2]- and [3+3]-annulations have been developed using readily available vinyl azides with 1,3-dicarbonyl compounds and cyclopropanols. Vinyl azides were successfully applied as a three-atom unit including one nitrogen to prepare various azaheterocycles via Mn(III)-catalyzed radical reactions.

引用

页码：377 / 381

页数：5

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