Photoinitiated multicomponent cascade reaction of N-heteroarenes with unactivated alkenes and trimethylsilyl azide

被引：14

作者：

Shen, Jiabin ^{[1
,2
]}

He, Lei ^{[1
]}

Liang, Chenfeng ^{[1
]}

Ouyang, Yani ^{[1
]}

Yue, Xiaoguang ^{[1
]}

Wu, Haifeng ^{[1
,2
]}

Xu, Jun ^{[3
,4
]}

Liu, Xiaogang ^{[3
,4
]}

Zhu, Qing ^{[2
]}

Zhang, Pengfei ^{[1
]}

机构：

[1] Hangzhou Normal Univ, Coll Mat Chem & Chem Engn, Hangzhou 311121, Peoples R China

[2] Zhejiang Univ Technol, Collaborat Innovat Ctr Yangtze River Delta Reg Gre, Hangzhou 310058, Peoples R China

[3] Natl Univ Singapore, Dept Chem, Singapore 117543, Singapore

[4] Natl Univ Singapore, Inst Hlth 1, Singapore 117543, Singapore

来源：

MOLECULAR CATALYSIS | 2022年 / 524卷

基金：

中国国家自然科学基金;

关键词：

Visible light; Multicomponent cascade reaction; N-heteroarenes; Quinoxalin-2(1H)-ones; VISIBLE-LIGHT PHOTOREDOX; METAL; QUINOXALIN-2(1H)-ONES; FUNCTIONALIZATION; PHOTOCATALYSIS; HETEROCYCLES; DIVERSITY; CHEMISTRY; ARYLATION; CATALYSIS;

D O I：

10.1016/j.mcat.2022.112330

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A visible-light-mediated multicomponent cascade reaction of heteroarenes with unactivated alkenes and TMSN3 has been developed. This approach gives a practical solution for the eco-friendly modification of N-heteroarenes with a high functional group tolerance and a broad substrate scope. This efficient, green strategy provides access to functional compounds that contain both a heteroarene skeleton and an organic azide structure.

引用

页数：8

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