We found that the improved structural order in hydrogenated amorphous silicon (a-Si:H) deposited by hot-wire chemical vapor deposition (HW-CVD) does not result in narrowing of the electronic band tail density of states. However, the features of light-induced effects are different from those in glow-discharge (GD-CVD) films. Upon light-soaking, (a) the photoconductivity (PC) does not change significantly, and (b) the Fermi level position moves up rather than down in most samples. These results are discussed in the context of possible defect complexes existing in an inhomogeneous network. (C) 2001 Elsevier Science B.V. All rights reserved.