Microwave and ultrasound assisted extraction of phytocompounds from black jamun pulp: Kinetic and thermodynamics characteristics

The present study focuses on the extraction of phenolic compounds, anthocyanin and antioxidants from black jamun pulp by microwave and ultrasound assisted extraction process. The microwave-assisted extraction was carried out for 240 s at microwave power level of 100-400 W. The yield of total anthocyanin and total phenolic content in the microwave assisted extraction process at 400 W power level after an extraction period of 240 s was 8.197 mg of C3G g(-1) and 37.671 40.632 mg GAE g(-1), respectively. The ultrasound assisted extraction was performed at temperatures of 40, 50, 60, and 70 degrees C for 150 min. In the ultrasound assisted extraction at a sonication temperature of 70 degrees C, the yield of anthocyanin was 8.525 mg of C3G g(-1), while the yield of the phenolic compound was 47.331 mg GAE g(-1). The pseudo-second order model was found to be the most suitable model to represent the extraction kinetics of anthocyanin, phenolic compounds, and antioxidant activity of black jamun pulp. The effective diffusion coefficient for ultrasound assisted extraction of phenolic components, anthocyanin, and antioxidant activity in the temperature range of 40-70 degrees C was 5.704 x 10(-12)-10.515 x 10(-12), 2.485 x 10(-12)-8.507 x 10(-12), and 2.061x 10(-12)-11.977 x 10(-12) m(2).s(-1) respectively. The negative Gibbs free energy change values for extraction of phenolic compounds and anthocyanin specified that the reaction was feasible and spontaneous. Thermodynamic parameters such as positive enthalpy change and positive entropy change indicated that the ultrasound assisted extraction process was endothermic and irreversible in nature.