Enhanced electrical conductivity in graphene-copper multilayer composite

被引:23
作者
Pan, Chaochao [1 ]
Gaur, Anand P. S. [1 ]
Lynn, Matthew [2 ]
Olson, Madison P. [1 ]
Ouyang, Gaoyuan [3 ]
Cui, Jun [1 ,3 ]
机构
[1] Iowa State Univ, Dept Mat Sci & Engn, Ames, IA 50011 USA
[2] Ames Lab, Sensit Instrument Facil, Ames, IA 50011 USA
[3] Ames Lab, Div Mat Sci & Engn, Ames, IA 50011 USA
关键词
ELECTRONIC-STRUCTURE; MECHANICAL-PROPERTIES; CARBON NANOTUBES; HIGH-QUALITY; MICROSTRUCTURE; RESISTIVITY; STRENGTH; FILMS;
D O I
10.1063/5.0073879
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
For many years, researchers have been trying to make a material more conductive than silver by incorporating carbon nanotubes or graphene into copper to form a composite material. However, after a decade-long effort, only a few groups reported successful results, raising concerns about the feasibility of this composite approach. Here, we report our effort to validate the multilayer graphene-copper composite approach for improving electrical conductivity. We demonstrate that, with an estimated 0.008 vol. % graphene addition, copper's electrical conductivity was improved to 104.2% of International Annealed Copper Standard (IACS) at room temperature. If the copper substrate used to make the multilayer composite is discounted using the parallel resistance model, the conductivity is calculated to be 185% IACS. This result could be further improved if the thickness of the copper layers can be further reduced. (c) 2022 Author(s). All article content, except where otherwise noted, is licensed under a Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/).
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页数:6
相关论文
共 49 条
[21]   First-principles study of the interaction and charge transfer between graphene and metals [J].
Khomyakov, P. A. ;
Giovannetti, G. ;
Rusu, P. C. ;
Brocks, G. ;
van den Brink, J. ;
Kelly, P. J. .
PHYSICAL REVIEW B, 2009, 79 (19)
[22]   Influence of the copper substrate roughness on the electrical quality of graphene [J].
Kwon, Gi Duk ;
Moyen, Eric ;
Lee, Yeo Jin ;
Kim, Young Woo ;
Baik, Seung Hyun ;
Pribat, Didier .
MATERIALS RESEARCH EXPRESS, 2017, 4 (01)
[23]   Conductive enhancement of copper/graphene composites based on high-quality graphene [J].
Li, Weiping ;
Li, Delong ;
Fu, Qiang ;
Pan, Chunxu .
RSC ADVANCES, 2015, 5 (98) :80428-80433
[24]   Large-Area Synthesis of High-Quality and Uniform Graphene Films on Copper Foils [J].
Li, Xuesong ;
Cai, Weiwei ;
An, Jinho ;
Kim, Seyoung ;
Nah, Junghyo ;
Yang, Dongxing ;
Piner, Richard ;
Velamakanni, Aruna ;
Jung, Inhwa ;
Tutuc, Emanuel ;
Banerjee, Sanjay K. ;
Colombo, Luigi ;
Ruoff, Rodney S. .
SCIENCE, 2009, 324 (5932) :1312-1314
[25]   Thickness dependence of resistivity for Cu films deposited by ion beam deposition [J].
Lim, JW ;
Mimura, K ;
Isshiki, M .
APPLIED SURFACE SCIENCE, 2003, 217 (1-4) :95-99
[26]   The solubility of C in solid Cu [J].
López, GA ;
Mittemeijer, E .
SCRIPTA MATERIALIA, 2004, 51 (01) :1-5
[27]   Giant intrinsic carrier mobilities in graphene and its bilayer [J].
Morozov, S. V. ;
Novoselov, K. S. ;
Katsnelson, M. I. ;
Schedin, F. ;
Elias, D. C. ;
Jaszczak, J. A. ;
Geim, A. K. .
PHYSICAL REVIEW LETTERS, 2008, 100 (01)
[28]  
National Bureau of Standards, 1914, CIRCULAR BUREAU STAN, V3rd, DOI [10.6028/NBS.CIRC.31-3, DOI 10.6028/NBS.CIRC.31-3]
[29]   Two-dimensional gas of massless Dirac fermions in graphene [J].
Novoselov, KS ;
Geim, AK ;
Morozov, SV ;
Jiang, D ;
Katsnelson, MI ;
Grigorieva, IV ;
Dubonos, SV ;
Firsov, AA .
NATURE, 2005, 438 (7065) :197-200
[30]   Electric field effect in atomically thin carbon films [J].
Novoselov, KS ;
Geim, AK ;
Morozov, SV ;
Jiang, D ;
Zhang, Y ;
Dubonos, SV ;
Grigorieva, IV ;
Firsov, AA .
SCIENCE, 2004, 306 (5696) :666-669