Correlation between boson peak and anomalous elastic behavior in GeO2 glass: An in situ Raman scattering study under high-pressure

被引：26

作者：

Deschamps, T. ^{[1
]}

Martinet, C. ^{[1
]}

de Ligny, D. ^{[1
]}

Bruneel, J. L. ^{[2
]}

Champagnon, B. ^{[1
]}

机构：

[1] Univ Lyon 1, Lab Phys Chim Mat Luminescents, CNRS UMR5620, F-69622 Villeurbanne, France

[2] Univ Bordeaux 1, CNRS UMR5255, Grp Spect Mol, Inst Sci Mol, F-33405 Talence, France

来源：

JOURNAL OF CHEMICAL PHYSICS | 2011年 / 134卷 / 23期

关键词：

DYNAMICS; SILICA; SIO2; TEMPERATURE; NEUTRON;

D O I：

10.1063/1.3599939

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

We present low-frequency Raman scattering of pure GeO2 glass under pressure up to 4 GPa, corresponding to an elastic transformation. Intensity variation and frequency shift of the boson peak are analysed and compared to the Debye model. The decrease of the boson peak intensity scaled by the Debye energy is correlated to the elastic anomalous properties under pressure up to 1.5 GPa, and interpreted as an elastic homogenisation process at the local scale. We emphasize similarities between a-GeO2 and a-SiO2 behavior under pressure, and compare our results to other experiments, numerical studies, and predictions of several models concerning amorphous systems. (C) 2011 American Institute of Physics. [doi:10.1063/1.3599939]

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页数：4

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