Novel homochiral holodirected three-dimensional lead(II) coordination polymer, [Pb2(μ-bpa)3(μ-NO3)2(NO3)2]n:: Spectroscopic, thermal fluorescence and structural studies

被引：20
|
作者：
Aslani, Alireza [1 ]
Morsali, Ali [1 ]
Zeller, Matthias [2 ]
机构：
[1] Tarbiat Modares Univ, Fac Sci, Dept Chem, Tehran, Iran
[2] Youngstown State Univ, Dept Chem, Youngstown, OH 44555 USA
来源：
SOLID STATE SCIENCES | 2008年 / 10卷 / 07期
关键词：
lead(II); coordination polymer; holodirected; homochiral;
D O I：
10.1016/j.solidstatesciences.2007.11.008
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A novel homochiral holodirected coordination polymer of lead(II) nitrate with the bridging ligand 1,2-bis(4-pyfidyl)ethane (bpa), [Pb-2(mu-bpa)(3)(mu-NO3)(2)(NO3)(2)](n) (1), has been synthesized and characterized by elemental analysis, FT-IR, thermal analysis and single crystal X-ray diffraction. In 1, the lead(II) ions are doubly bridged by both bpa and nitrate ligands into a chiral infinite three-dimensional polymeric network. There are two different nine- and eight-coordinate geometries around the lead(II) ion in 1, in which the lead(H) ions have a less common holodirected geometry. Solid-state luminescent spectra of compound 1 indicate intense fluorescent emission at ca. 434 nm. (C) 2007 Elsevier Masson SAS. All rights reserved.
引用
收藏
页码：854 / 858
页数：5
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