Photomechanical Motion of Furylfulgide Crystals

被引:82
作者
Koshima, Hideko [1 ]
Nakaya, Hidemitsu [1 ]
Uchimoto, Hidetaka [1 ]
Ojima, Naoko [1 ]
机构
[1] Ehime Univ, Grad Sch Sci & Engn, Dept Mat Sci & Biotechnol, Matsuyama, Ehime 7908577, Japan
关键词
SHAPE CHANGES; PHOTOCHROMISM; LIGHT; FULGIDES;
D O I
10.1246/cl.2012.107
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Plate-like microcrystals of a photochromic furylfulgide bend toward the light upon UV irradiation and then straighten upon visible light irradiation. The reversible bending was observed over 200 cycles of alternating irradiation with UV and visible light. The mechanism of bending could be explained by the X-ray crystallographic data.
引用
收藏
页码:107 / 109
页数:3
相关论文
共 22 条
[1]   Photochemically driven shape changes of crystalline organic nanorods [J].
Al-Kaysi, Rabih O. ;
Mueller, Astrid M. ;
Bardeen, Christopher J. .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2006, 128 (50) :15938-15939
[2]   Reversible photoinduced shape changes of crystalline organic nanorods [J].
Al-Kaysi, Rabih O. ;
Bardeen, Christopher J. .
ADVANCED MATERIALS, 2007, 19 (09) :1276-+
[3]  
Balzani V., 2008, MOL DEVICES MACHINES, DOI DOI 10.1002/9783527621682
[4]   X-ray diffraction analysis of photochromic reaction of fulgides: Crystalline state reaction induced by two-photon excitation [J].
Harada, Jun ;
Nakajima, Ryo ;
Ogawa, Keiichiro .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (22) :7085-7091
[5]   Photochromism and molecular mechanical devices [J].
Irie, Masahiro .
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 2008, 81 (08) :917-926
[6]   Molecular conformation and structural changes in crystalline photochromism of 3-furylfulgide [J].
Khedhiri, L ;
Corval, A ;
Casalegno, R ;
Rzaigui, M .
JOURNAL OF PHYSICAL CHEMISTRY A, 2004, 108 (36) :7473-7478
[7]   Photochromism of furylfulgide in a single-crystalline phase [J].
Kobatake, S ;
Irie, M .
CHEMISTRY LETTERS, 2004, 33 (07) :904-905
[8]   Rapid and reversible shape changes of molecular crystals on photoirradiation [J].
Kobatake, Seiya ;
Takami, Shizuka ;
Muto, Hiroaki ;
Ishikawa, Tomoyuki ;
Irie, Masahiro .
NATURE, 2007, 446 (7137) :778-781
[9]   High-Convertible Photochromism of a Diarylethene Single Crystal Accompanying the Crystal Shape Deformation [J].
Kobatake, Seiya ;
Hasegawa, Hiroki ;
Miyamura, Kentaro .
CRYSTAL GROWTH & DESIGN, 2011, 11 (04) :1223-1229
[10]   Photomechanical bending of 4-aminoazobenzene crystals [J].
Koshima, Hideko ;
Ojima, Naoko .
DYES AND PIGMENTS, 2012, 92 (02) :798-801