Synthesis, Crystal Structure and Luminescence of a Novel Cadmium(II) Coordination Polymer with 5-Connected nov Net

被引：0

作者：

Wang Peng-Fei ^{[1
]}

Wu Xiao-Shuo ^{[1
]}

Wu Qiu-Yan ^{[1
]}

Wang Xin ^{[1
]}

机构：

[1] Chizhou Coll, Ctr Chem Mat & Engn Expt, Dept Chem & Food Sci, Chizhou 247000, Peoples R China

来源：

CHINESE JOURNAL OF STRUCTURAL CHEMISTRY | 2011年 / 30卷 / 12期

基金：

中国国家自然科学基金;

关键词：

cadmium compound; 5-sulfosalicylic acid; luminescent property; topology; METAL-ORGANIC FRAMEWORKS; 5-SULFOSALICYLIC ACID; LIGANDS; COMPLEXES; NETWORK;

D O I：

暂无

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A novel interesting coordination polymer, [Cd(HSSA)(2-bimb)(2)]center dot 3H(2)O (1, H(3)SSA = 5-sulfosalicylic acid, 2-bimb = 1,2-bis(imidazol-1-ylmethyl)-benzene), has been synthesized and structurally characterized. Compound 1 crystallizes in the monoclinic system, space group P2(1)/n with a = 10.8653(10), b = 19.4100(17), c = 17.4414(17) angstrom, beta = 91.944(2)degrees, V = 3676.2(6) angstrom(3), Z = 4, C(35)H(38)CdN(8)O(9)S, M(r) = 859.19, D(c) = 1.552 g/cm(3), mu = 0.717 mm(-1), S = 0.999, F(000) = 1760, R = 0.0531 and wR = 0.1078. The compound features a rare three-dimensional (3D) 5-connected nov topology. In addition, compound 1 exhibits strong photoluminescent emission at room temperature.

引用

页码：1709 / 1714

页数：6

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