Effect of Pretreatment Time in Dry Reforming over Ni/TiO2 Catalyst

被引:6
作者
Kim, Sung Su [1 ]
Choi, Hyun Jin [1 ]
Hong, Sung Chang [1 ]
机构
[1] Kyonggi Univ, Dept Environm Energy Syst Engn, Suwon 442760, Gyeonggi Do, South Korea
关键词
Reforming; Ni; TiO2; Catalyst; CO2; CARBON-DIOXIDE; SYNTHESIS GAS; PARTIAL OXIDATION; METHANE; SURFACE;
D O I
10.1252/jcej.11we080
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
In this study, the effects of the pretreatment time on the properties of Ni/TiO2 catalysts are examined. The optimum time has been determined to be below 3 h with regard to the catalytic activity. The difference between the CH4 conversion and CO2 conversion drastically increased for a catalyst pretreated for 4 h. The activity tests of the reverse water gas shift reaction (RWGS), temperature-programmed hydrogenation, and elementary reaction of dry reforming over the catalysts showed that the difference between the two conversions was attributed to the high RWGS reaction rate.
引用
收藏
页码:41 / 45
页数:5
相关论文
共 15 条
[1]   PARTIAL OXIDATION OF METHANE TO SYNTHESIS GAS-USING CARBON-DIOXIDE [J].
ASHCROFT, AT ;
CHEETHAM, AK ;
GREEN, MLH ;
VERNON, PDF .
NATURE, 1991, 352 (6332) :225-226
[2]   Effect of adding CaO to ZrO2 support on nickel catalyst activity in dry reforming of methane [J].
Bellido, Jorge D. A. ;
De Souza, Jose E. ;
M'Peko, Jean-Claude ;
Assaf, Elisabete M. .
APPLIED CATALYSIS A-GENERAL, 2009, 358 (02) :215-223
[3]   CO2 reforming of CH4 [J].
Bradford, MCJ ;
Vannice, MA .
CATALYSIS REVIEWS-SCIENCE AND ENGINEERING, 1999, 41 (01) :1-42
[4]   Partial oxidation of methane and carbon dioxide reforming with methane in corona discharge with/without Pt/KL catalyst [J].
Chavadej, S ;
Supat, K ;
Lobban, LL ;
Mallinson, RG .
JOURNAL OF CHEMICAL ENGINEERING OF JAPAN, 2005, 38 (03) :163-170
[5]   Carbon dioxide reforming of methane reaction catalyzed by stable nickel copper catalysts [J].
Chen, HW ;
Wang, CY ;
Yu, CH ;
Tseng, LT ;
Liao, PH .
CATALYSIS TODAY, 2004, 97 (2-3) :173-180
[6]   Characterization of surface processes at the Ni-based catalyst during the methanation of biomass-derived synthesis gas: X-ray photoelectron spectroscopy (XPS) [J].
Czekaj, Izabela ;
Loviat, Francois ;
Raimondi, Fabio ;
Wambach, Joerg ;
Biollaz, Serge ;
Wokaun, Alexander .
APPLIED CATALYSIS A-GENERAL, 2007, 329 :68-78
[7]   The effect of CeO2 on the surface and catalytic properties of Pt/CeO2-ZrO2 catalysts for methane dry reforming [J].
Damyanova, S. ;
Pawelec, B. ;
Arishtirova, K. ;
Martinez Huerta, M. V. ;
Fierro, J. L. G. .
APPLIED CATALYSIS B-ENVIRONMENTAL, 2009, 89 (1-2) :149-159
[8]   Methane steam reforming in a zirconia membrane reactor [J].
Kusakabe, Katsuki ;
Mizoguchi, Hitomi ;
Eda, Tomokazu .
JOURNAL OF CHEMICAL ENGINEERING OF JAPAN, 2006, 39 (04) :444-447
[9]   Catalytic dry reforming of methane over high surface area ceria [J].
Laosiripojana, N ;
Assabumrungrat, S .
APPLIED CATALYSIS B-ENVIRONMENTAL, 2005, 60 (1-2) :107-116
[10]   Catalytic performance of novel Ni catalysts supported on SiC monolithic foam in carbon dioxide reforming of methane to synthesis gas [J].
Liu, Haitao ;
Li, Shunqing ;
Zhang, Sanbing ;
Wang, Jianmin ;
Zhou, Guojun ;
Chen, Long ;
Wang, Xiaolai .
CATALYSIS COMMUNICATIONS, 2008, 9 (01) :51-54