In Situ Electrochemical Cells to Study the Oxygen Evolution Reaction by Near Ambient Pressure X-ray Photoelectron Spectroscopy

被引:39
作者
Streibel, Verena [1 ]
Haevecker, Michael [1 ,2 ]
Yi, Youngmi [1 ,2 ]
Velez, Juan J. Velasco [1 ,2 ]
Skorupska, Katarzyna [1 ,2 ]
Stotz, Eugen [1 ]
Knop-Gericke, Axel [1 ]
Schloegl, Robert [1 ,2 ]
Arrigo, Rosa [3 ]
机构
[1] Max Planck Gesell, Fritz Haber Inst, Dept Inorgan Chem, Faradayweg 4-6, D-14195 Berlin, Germany
[2] Max Planck Inst Chem Energiekonvers, Dept Heterogeneous React, Stiftstr 34-36, D-45470 Mulheim, Germany
[3] Diamond Light Source Ltd, Harwell Sci & Innovat Campus, Didcot OX 11 0DE, Oxon, England
关键词
Near ambient pressure X-ray photoelectron spectroscopy (NAP-XPS); Electrochemistry; Oxygen evolution reaction (OER); Low temperature polymeric electrolyte electrode assembly; Platinum; Iridium; ELECTRONIC-STRUCTURE; PLATINUM; IRIDIUM; OXIDE; OXIDATION; WATER; INTERFACE; MANGANESE; FILMS; REDUCTION;
D O I
10.1007/s11244-018-1061-8
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
In this contribution, we report the development of in situ electrochemical cells based on proton exchange membranes suitable for studying interfacial structural dynamics of energy materials under operation by near ambient pressure X-ray photoelectron spectroscopy. We will present both the first design of a batch-type two-electrode cell prototype and the improvements attained with a continuous flow three-electrode cell. Examples of both sputtered metal films and carbon-supported metal nanostructures are included demonstrating the high flexibility of the cells to study energy materials. Our immediate focus was on the study of the oxygen evolution reaction, however, the methods described herein can be broadly applied to reactions relevant in energy conversion and storage devices.
引用
收藏
页码:2064 / 2084
页数:21
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