Photodegradation of organic dyes by CeO2/Bi2WO6 nanocomposite and its physicochemical properties investigation

The CeO2/Bi2WO6 nanocomposite was synthesized by coupling of precipitation and hydrothermal methods. A detailed study of the physicochemical properties of CeO2/Bi2WO6 nanocomposite were investigated by XRD, TEM, BET-specific surface area, UV-vis DRS, XPS, zeta potential, and PL techniques. The photocatalytic activities of CeO2/Bi2WO6 nanocomposite was evaluated for the degradation of methylene blue (MB), rhodamine B (RhB) and the mixed dyes of MB and RhB under visible light irradiation. The CeO2/Bi2WO6 nanocomposite presents excellent photocatalytic degradation of MB, RhB, and the mixed dyes of MB and RhB. The enhanced photocatalytic activity was originated from the migration efficiency of photogenerated charge carriers on the interface of CeO2 and Bi2WO6. Moreover, the active species trapping experiments demonstrated holes (h(+)) and hydroxyl radical (OH center dot) were major active species in the degradation of RhB and MB, respectively. Herein, we also investigate the produced hydroxyl radical as a main oxidant in photocatalysis process for improving photocatalytic performance. Moreover, the CeO2/Bi2WO6 nanocomposites shows excellent cycle stability toward continuous five cycles runs of photocatalytic experiment for dyes degradation. The possible photocatalytic mechanism of CeO2/Bi2WO6 nanocomposite was described. (C) 2016 Elsevier Ltd and Techna Group S.r.l. All rights reserved.