Chemical synthesis of graphite bis(perfluoropinacolato)borate and graphite bis(hexafluorohydroxyisobutyrato)borate intercalation compounds

被引：5

作者：

Katinonkul, Watcharee ^{[1
]}

Lerner, Michael M. ^{[1
]}

机构：

[1] Oregon State Univ, Dept Chem, Corvallis, OR 97331 USA

来源：

CARBON | 2007年 / 45卷 / 13期

关键词：

D O I：

10.1016/j.carbon.2007.07.020

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Graphite chelate borate intercalation compounds, CxB[OC(CF3)(2)C(CF3)(2)O](2) center dot delta F and CxB[OC(CF3)(2)C(O)O](2) center dot delta F, are prepared for the first time by chemical oxidation of flaky graphite with fluorine gas in the presence of a solution of the intercalate anion in anhydrous hydrofluoric acid. Powder XRD data indicate that products up to stage 1 with gallery heights, d(i) = 1.43-1.45 nm are formed. The compositions of CxB[OC(CF3)(2)C(CF3)(2)O](2)center dot delta F and CxB[OC(CF3)(2)C(O)O](2)F center dot delta F are determined using B and F elemental analyses. Thermogravimetric analyses indicate the graphene sheets begin to decompose before intercalate thermolysis is complete. (C) 2007 Elsevier Ltd. All rights reserved.

引用

页码：2672 / 2677

页数：6

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