Photochemical bissilylation of C60 with disilane

被引：52

作者：

Akasaka, T ^{[1
]}

Suzuki, T

Maeda, Y

Ara, M

Wakahara, T

Kobayashi, K

Nagase, S

Kako, M

Nakadaira, Y

Fujitsuka, M

Ito, O

机构：

[1] Niigata Univ, Grad Sch Sci & Technol, Niigata 9502181, Japan

[2] Tokyo Metropolitan Univ, Grad Sch Sci, Dept Chem, Tokyo 1920397, Japan

[3] Univ Electrocommun, Dept Chem, Tokyo 1828585, Japan

[4] Tohoku Univ, Inst Chem React Sci, Aoba Ku, Sendai, Miyagi 9808577, Japan

[5] Inst Mol Sci, Okazaki, Aichi 4448585, Japan

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1999年 / 64卷 / 02期

关键词：

D O I：

10.1021/jo981689h

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The photochemical reaction of C-60 with disilane I affords the adduct 2 as a bissilylated product. The unique redox properties of 2 are reported by means of differential pulse voltammetry. The compound 2 was characterized by NMR, IR, and UV-vis spectroscopies. Spectroscopic and theoretical investigation strongly support the 1,16-addition structure having C-2 symmetry which results from addition at the 1,16 positions in C-60 The results are reasonably accounted for by the generation of a silyl radical which is responsible for the formation of 2.

引用

页码：566 / 569

页数：4

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