Protection Strategies for the Conversion of Biobased Furanics to Chemical Building Blocks

被引：20

作者：

Coumans, Ferdy J. A. G. ^{[1
]}

Overchenko, Zhanna ^{[1
]}

Wiesfeld, Jan J. ^{[2
]}

Kosinov, Nikolay ^{[1
]}

Nakajima, Kiyotaka ^{[2
]}

Hensen, Emiel J. M. ^{[1
]}

机构：

[1] Eindhoven Univ Technol, Lab Inorgan Chem & Catalysis, NL-5600 MB Eindhoven, Netherlands

[2] Hokkaido Univ, Inst Catalysis, Sapporo, Hokkaido 0010021, Japan

来源：

ACS SUSTAINABLE CHEMISTRY & ENGINEERING | 2022年 / 10卷 / 10期

基金：

日本学术振兴会;

关键词：

Biomass; Chemical building blocks; Furanics; Humins; Side reactions; Protection; DIELS-ALDER REACTIONS; MOLECULAR-STRUCTURE; BIOMASS CONVERSION; ACID; HUMINS; CATALYSTS; PLATFORM; OXIDATION; HMF; ETHERIFICATION;

D O I：

10.1021/acssuschemeng.1c06723

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

In recent years, the urgency to replace fossil-based resources by renewablebiomass for obtaining chemical building blocks has only increased. Carbohydrate-derivedfuranic compounds are regarded as promising platforms for a renewable value chain. Thehigh reactivity of such biobased intermediates requires the development of novel catalyticchemistry to enhance product yield. The protection of reactive functional groupsprovides a way to improve the product selectivity. Such protection strategies are commonpractice in the synthesis offine chemicals and pharmaceuticals but are not fully exploredfor the conversion of furanic compounds. In this perspective, several examples ofprotection strategies focusing on the selective passivation of 5-HMF are discussed.Formation and removal of these protection groups are highlighted as well as theapplication of the neutralized 5-HMF in further processing. A guide for selecting theappropriate protection strategy depending on the targeted chemistry and operatingconditions is provided.

引用

页码：3116 / 3130

页数：15

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