In situ formation of ligand and catalyst -: application in ruthenium-catalyzed enantioselective reduction of ketones

被引:44
作者
Västilä, P [1 ]
Wettergren, J [1 ]
Adolfsson, H [1 ]
机构
[1] Stockholm Univ, Dept Organ Chem, Arrhenius Lab, SE-10691 Stockholm, Sweden
关键词
D O I
10.1039/b505516d
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The direct in situ formation of highly efficient ruthenium-catalysts for the asymmetric reduction of ketones was obtained by combining chiral ligand building blocks with a ruthenium precursor.
引用
收藏
页码:4039 / 4041
页数:3
相关论文
共 33 条
[1]   (1S,3R,4R)-2-azanorbornylmethanol, an efficient ligand for ruthenium-catalyzed asymmetric transfer hydrogenation of ketones [J].
Alonso, DA ;
Guijarro, D ;
Pinho, P ;
Temme, O ;
Andersson, PG .
JOURNAL OF ORGANIC CHEMISTRY, 1998, 63 (08) :2749-2751
[2]   2-azanorbornyl alcohols: Very efficient ligands for ruthenium-catalyzed asymmetric transfer hydrogenation of aromatic ketones [J].
Alonso, DA ;
Nordin, SJM ;
Roth, P ;
Tarnai, T ;
Andersson, PG ;
Thommen, M ;
Pittelkow, U .
JOURNAL OF ORGANIC CHEMISTRY, 2000, 65 (10) :3116-3122
[3]   Selective hydrogenation for fine chemicals: Recent trends and new developments [J].
Blaser, HU ;
Malan, C ;
Pugin, B ;
Spindler, F ;
Steiner, H ;
Studer, M .
ADVANCED SYNTHESIS & CATALYSIS, 2003, 345 (1-2) :103-151
[4]   Highly enantioselective ruthenium-catalyzed reduction of ketones employing readily available peptide ligands [J].
Bogevig, A ;
Pastor, IM ;
Adolfsson, H .
CHEMISTRY-A EUROPEAN JOURNAL, 2004, 10 (01) :294-302
[5]   Rutheuium(II)-catalyzed asymmetric transfer hydrogenation of carbonyl compounds with 2-propanol and ephedrine-type ligands [J].
Everaere, K ;
Mortreux, A ;
Carpentier, JF .
ADVANCED SYNTHESIS & CATALYSIS, 2003, 345 (1-2) :67-77
[6]   Nitrogen-containing ligands for asymmetric homogeneous and heterogeneous catalysis [J].
Fache, F ;
Schulz, E ;
Tommasino, ML ;
Lemaire, M .
CHEMICAL REVIEWS, 2000, 100 (06) :2159-2231
[7]   Ruthenium(II)-catalyzed asymmetric transfer hydrogenation of ketones using a formic acid-triethylamine mixture [J].
Fujii, A ;
Hashiguchi, S ;
Uematsu, N ;
Ikariya, T ;
Noyori, R .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1996, 118 (10) :2521-2522
[8]   Combinatorial libraries of chiral ligands for enantioselective catalysis [J].
Gennari, C ;
Piarulli, U .
CHEMICAL REVIEWS, 2003, 103 (08) :3071-3100
[9]  
Haas K, 2002, Z ANORG ALLG CHEM, V628, P788, DOI 10.1002/1521-3749(200205)628:4<788::AID-ZAAC788>3.0.CO
[10]  
2-V