Color-Tunable Photoluminescent Fullerene Nanoparticles

被引:53
作者
Jeong, Jinyoung [1 ]
Jung, Juyeon [1 ]
Choi, Mijin [1 ]
Kim, Ju Whan [1 ]
Chung, Sang J. [1 ]
Lim, Sujin [1 ]
Lee, Han [1 ]
Chung, Bong Hyun [1 ]
机构
[1] Univ Sci & Technol, BioNanotechnol Res Ctr, Korea Res Inst Biosci & Biotechnol Nanobiotechnol, Sch Engn, Taejon 305806, South Korea
基金
新加坡国家研究基金会;
关键词
fullerene; nanoparticle; color-tunable photoluminescence; water-solubility; ROOM-TEMPERATURE; C-60; FULLEROL; FLUORESCENCE; WATER; DERIVATIVES; CHEMISTRY;
D O I
10.1002/adma.201104772
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Highly water-soluble and color-tunable photoluminescent fullerene nanoparticles are synthesized by using tetraethylene glycol (TEG) and lithium hydroxide as a catalyst. The maximum PL emission changes depend on the contents of the remaining π-conjugation in oxidized C60, which is partially covalently conjugated with TEG. The PL behavior is attributed to an electronic transition change due to the distortion of symmetrical C60. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码:1999 / 2003
页数:5
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